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Volumn 37, Issue 26, 1998, Pages 6814-6826

Mixed-Valence CuI-CuII and Heterodimetallic CuI-MII Bis(carboxylate-bridged) Complexes: Structural, Electrochemical, and Spectroscopic Investigations

Author keywords

[No Author keywords available]

Indexed keywords


EID: 0001090154     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic980763b     Document Type: Article
Times cited : (56)

References (71)
  • 20
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    • II mixed-valence "acetate/methanol" complex has been reported, and support for a delocalized structure at room temperature and at 77 K was acquired by EPR spectroscopy. This complex was never isolated, however, and it disproportionated to a large extent upon cooling below ∼-50 °C as judged by the presence of a significant mononuclear Cu(II) impurity in the EPR spectrum. See: Sigwart, C.; Hemmerich, P.; Spence, J. T. Inorg. Chem. 1968, 7, 2545-1548.
    • (1968) Inorg. Chem. , vol.7 , pp. 2545-11548
    • Sigwart, C.1    Hemmerich, P.2    Spence, J.T.3
  • 21
    • 0038298477 scopus 로고    scopus 로고
    • (b) In more recent work, the same or a closely related mixed-valence species was generated photochemically or electrochemically from Cu(II) acetate, and the product was characterized by UV-vis and EPR spectroscopy, See: (i) Toledo, I.; Arancibia, M.; Andrade, C.; Crivelli, I. Polyhedron 1998, 77, 173-178 and Crivelli, I. G.; Andrade, C. G. Inorg. Chim. Acta 1993, 203, 115-120.
    • (1998) Polyhedron , vol.77 , pp. 173-178
    • Toledo, I.1    Arancibia, M.2    Andrade, C.3    Crivelli, I.4
  • 22
    • 0006607739 scopus 로고
    • (b) In more recent work, the same or a closely related mixed-valence species was generated photochemically or electrochemically from Cu(II) acetate, and the product was characterized by UV-vis and EPR spectroscopy, See: (i) Toledo, I.; Arancibia, M.; Andrade, C.; Crivelli, I. Polyhedron 1998, 77, 173-178 and Crivelli, I. G.; Andrade, C. G. Inorg. Chim. Acta 1993, 203, 115-120.
    • (1993) Inorg. Chim. Acta , vol.203 , pp. 115-120
    • Crivelli, I.G.1    Andrade, C.G.2
  • 25
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    • note
    • 3N.
  • 46
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    • Bruker Analytik GmbH: Karlsruhe, FRG
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    • (1995) SHELXTL: Structure Analysis Program, 5.0
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    • Merck Research Laboratories: Whitehouse Station, NJ
    • The Merck Index, 12th ed.; Budavari, S., Ed.; Merck Research Laboratories: Whitehouse Station, NJ, 1996.
    • (1996) The Merck Index, 12th Ed.
    • Budavari, S.1
  • 56
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    • note
    • 3, Z = 4, T = 188 K, R = 14.12%, wR2 = 40.36. This structure was not fully refined due to major disorder of the two dichloroethane molecules in the crystal lattice.
  • 71
    • 1842708880 scopus 로고    scopus 로고
    • See Supporting Information for contour plots of the SOMO and SHOMO and for the fragment molecular orbital and Walsh diagrams
    • See Supporting Information for contour plots of the SOMO and SHOMO and for the fragment molecular orbital and Walsh diagrams.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.