Neutral square-planar olefin/alkyl platinum(ii) complexes containing a N,N′-imino-amide ligand. Experimental and theoretical evidence of relevant π-back-donation in the platinum-olefin bond

Organometallics

Volumn 23, Issue 9, 2004, Pages 2137-2145

  Cavallo, Luigi ^a   Macchioni, Alceo ^b   Zuccaccia, Cristiano ^b   Zuccaccia, Daniele ^b   Orabona, Ida ^c   Ruffo, Francesco ^c  

^a UNIVERSITY OF SALERNO   (Italy)

^b UNIVERSITY OF PERUGIA   (Italy)

^c UNIVERSITY OF NAPLES FEDERICO II   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

CORRELATION METHODS; ISOMERS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PARAMETER ESTIMATION; PROBABILITY DENSITY FUNCTION; PROTONS; SOLUTIONS; SYNTHESIS (CHEMICAL); THERMAL EFFECTS; X RAY DIFFRACTION;

PROTON ABSTRACTION; SCALAR COUPLING; SPATIAL ORIENTATION; SQUARE-PLANAR COORDINATION;

PLATINUM COMPOUNDS;

EID: 2442532947     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om049968k     Document Type: Article

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10. "M" and "0" indicate groups that stay in cis positions with respect to methyl and olefin groups, respectively, "u" and "d" discriminate the up and down isopropyl orientations with respect to the olefin R group. Finally, "b" and "f" stand for backward and forward with respect to the plane containing the two phenyl groups (assumed to be coplanar).
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