Alkene and alkyne reactivity over a metal-oxo surface modeled by calix[4]arene-tungsten(IV): formation of 1-metallacyclopropene and alkylidene complexes

Organometallics

Volumn 19, Issue 24, 2000, Pages 5218-5230

  Guillemot, Geoffroy ^a  

^a UNIVERSITY OF LAUSANNE   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; COMPUTER SIMULATION; FREE RADICALS; INFRARED SPECTROSCOPY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OLEFINS; REACTION KINETICS; SPECTROPHOTOMETRY; SYNTHESIS (CHEMICAL); X RAY CRYSTALLOGRAPHY;

ALKYLIDENE COMPLEXES; ALKYNE; ANCILLARY LIGAND; CALIXARENE-TUNGSTEN; DENSITY FUNCTIONAL THEORY APPROACH; DEPROTONATION; METAL-OXO SURFACE; METALLACYCLOPROPENE; SOFTWARE PACKAGE SHELFX93; SOFTWARE PACKAGE SHELX76;

ORGANOMETALLICS;

EID: 0034316415     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0006155     Document Type: Article

References (2)

1. (a) Thomas, J. M.; Thomas, W. J. Principles and Practice of Heterogeneous Catalysis; VCH: Weinheim, Germany, 1997.
2. (b) Cox, P. A. Transition Metal Oxides: An Introduction to their Electronic Structure and Properties; Oxford University Press: New York, 1992.