Highly stereoselective synthesis of (1E)-2-melethyl-1,3-dienes by palladium-catalyzed trans-selective cross-coupling of 1,1-dibromo-1-alkenes with alkenylzine reagents

Angewandte Chemie - International Edition

Volumn 43, Issue 17, 2004, Pages 2259-2263

  Zeng, Xingzhong ^a   Qian, Mingxing ^a   Hu, Qian ^a   Negishi, Ei Ichi ^a  

^a PURDUE UNIVERSITY   (United States)

Author keywords

Carbene ligands; Cross coupling; Dienes; Methylation; Palladium

Indexed keywords

ALKYLATION; ISOMERIZATION; PALLADIUM; POLYCYCLIC AROMATIC HYDROCARBONS;

METHYLATION; NITROGEN-HETEROCYCLIC CARBEN (NHC); STEREOISOMERIZATION;

STEREOCHEMISTRY;

ACETONE; ALKADIENE; ALKENE DERIVATIVE; BROMINE DERIVATIVE; CARBENE; PALLADIUM; ZINC; ALKENE; ANTIINFECTIVE AGENT; ANTINEOPLASTIC AGENT; CAROTENOID; DYES, REAGENTS, INDICATORS, MARKERS AND BUFFERS;

ALKYLATION; ARTICLE; METHYLATION; STEREOISOMERISM; CHEMISTRY; SYNTHESIS;

ALKENES; ANTI-BACTERIAL AGENTS; ANTINEOPLASTIC AGENTS; CAROTENOIDS; INDICATORS AND REAGENTS; PALLADIUM; STEREOISOMERISM; ZINC;

EID: 4043088534     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200353022     Document Type: Article

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