Highly selective synthesis of (E)-3-methyl-1-trialkylsilyl-3-en-1-ynes via trans-selective alkynylation catalyzed by Cl2Pd(DPEphos) and stereospecific methylation with methylzincs catalyzed by Pd(tBu 3P)2

Organic Letters

Volumn 5, Issue 11, 2003, Pages 1825-1828

  Shi, Ji Cheng ^a   Zeng, Xingzhong ^a   Negishi, Ei Ichi ^a  

^a PURDUE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKADIENE; ALKENE; ALKYNE; PALLADIUM COMPLEX; DYES, REAGENTS, INDICATORS, MARKERS AND BUFFERS; ORGANOMETALLIC COMPOUND; PALLADIUM; SILANE DERIVATIVE;

ALKYNYLATION; ARTICLE; CATALYSIS; CHEMICAL MODIFICATION; CONJUGATION; METHYLATION; STEREOSPECIFICITY; SYNTHESIS; CHEMISTRY; STEREOISOMERISM;

ALKYNES; CATALYSIS; INDICATORS AND REAGENTS; METHYLATION; ORGANOMETALLIC COMPOUNDS; PALLADIUM; SILANES; STEREOISOMERISM;

EID: 0041350417     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol030017x     Document Type: Article

References (44)

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