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Volumn 693, Issue 6, 2008, Pages 1081-1095

Heterocarbenoids of germanium and tin and their polyhedral oxidation products: The case for thermodynamic product control in Group 14 chalcogenides

Author keywords

Base stabilized double bonds; Germylene; Group 14 chalcogenides; Heterocarbenoids; Kinetically stabilized double bonds; Stannylene

Indexed keywords

AMIDES; GERMANIUM; THERMODYNAMICS; TIN;

EID: 39649109656     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2007.12.031     Document Type: Article
Times cited : (22)

References (77)
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    • note
    • Although the "double-bond rule" is often cited in this context, it has never been stated explicitly as a rule in printed form. For a more detailed discussion, see Ref. [64].
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    • note
    • Attempts to refine the structure as a pseudo-merohedrally, cubically twinned, orthorhombic crystal of space group Pbca failed. The refinement was not stable.
  • 64
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    • Manuscript in preparation.
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    • note
    • Parkin has noted that for transition metal chalcogenides the tendency to dimerize is exactly reversed, and that this is likely due to the greater polarity of the Group 14 element-to-chalcogen bond. See Ref. [34].
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    • note
    • The Ge{double bond, long}E moities shown were obtained from compounds Ge-O (2), Ge{double bond, long}S (3), Ge{double bond, long}Se (F), and Ge{double bond, long}Te (F). The germanium-oxide bond is a bridging bond, and the van der Waals radius may therefore be somewhat smaller than if it had been a terminal Ge{double bond, long}O bond.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.