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note
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Although the "double-bond rule" is often cited in this context, it has never been stated explicitly as a rule in printed form. For a more detailed discussion, see Ref. [64].
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62
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39649118060
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note
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Attempts to refine the structure as a pseudo-merohedrally, cubically twinned, orthorhombic crystal of space group Pbca failed. The refinement was not stable.
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64
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39649111159
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Manuscript in preparation.
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Manuscript in preparation.
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68
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39649103052
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note
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Parkin has noted that for transition metal chalcogenides the tendency to dimerize is exactly reversed, and that this is likely due to the greater polarity of the Group 14 element-to-chalcogen bond. See Ref. [34].
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69
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39649087853
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note
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The Ge{double bond, long}E moities shown were obtained from compounds Ge-O (2), Ge{double bond, long}S (3), Ge{double bond, long}Se (F), and Ge{double bond, long}Te (F). The germanium-oxide bond is a bridging bond, and the van der Waals radius may therefore be somewhat smaller than if it had been a terminal Ge{double bond, long}O bond.
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71
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39649092147
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