The synthesis and structure of {[η4-Me8taa]Sn(μ-O)}2: A bridging oxo complex in a system that yields terminal sulfido and selenido counterparts

Chemical Communications

Volumn , Issue 7, 1998, Pages 751-752

  Kuchta, Matthew C ^a   Hascall, Tony ^a   Parkin, Gerard ^a  

^a Columbia University ^*  (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001940578     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/a709065j     Document Type: Article

References (12)

1. T. M. Trnka and G. Parkin, Polyhedron, 1997, 16, 1031;
2. G. Parkin, Prog. Inorg. Chem., 1998, 47, 1.
3. M. C. Kuchta and G. Parkin, Coord. Chem. Rev., in press.
4. M. C. Kuchta and G. Parkin, Inorg. Chem., 1997, 36, 2492 and unpublished results.
5. M. C. Kuchta and G. Parkin, J. Am. Chem. Soc., 1995, 117, 12651.
6. M. C. Kuchta and G. Parkin, J. Chem. Soc., Chem. Commun., 1994, 1351.
7. M. C. Kuchta and G. Parkin, J. Am. Chem. Soc., 1994, 116, 8372.
8. Related porphyrin complexes (POR)SnE (E = S, Se) have also been synthesized; see: R. Guilard, C. Ratii, J.-M. Barbe, D. Dubois and K. M. Kadish, Inorg. Chem., 1991, 30, 1537.
9. 3), 4.44 (2 CH), 6.68 (4 CH).
10. 2 = 0.0983 [I > 2σ(I)], room temp. CCDC 182/787.
11. 8taa]Sn(μ-O)}2 [1.987(5) and 2.001(5) Å] compare favorably with the CSD mean (1.98 Å). The search was performed using CSD Version 5.13 for Sn-O interactions with two-coordinate oxygen. 3D Search and Research Using the Cambridge Structural Database, E. H. Allen and O. Kennard, Chem. Des. Automat. News, 1993, vol. 8(1), pp. 1 and 31-37.
12. A. G. Davies and P. J. Smith, in Comprehensive Organometallic Chemistry, ed. G. Wilkinson, F. G. A. Stone and E. W. Abel, Pergamon, New York, 1982, vol. 2, ch. 11, p. 573.