Cubane complexes with two (or more) group 14-group 16 double bonds: Synthesis and X-ray structures of Sn4Se2(NtBu)4 and Ge4Se3(NtBu)4

European Journal of Inorganic Chemistry

Volumn , Issue 10, 2003, Pages 1857-1860

  Chivers, Tristram ^a   Clark, Timothy J ^a   Krahn, Mark ^a   Parvez, Masood ^a   Schatte, Gabriele ^a  

^a UNIVERSITY OF CALGARY   (Canada)

Author keywords

Germanium; Main group elements; Multiple bonds; Selenium; Tin

Indexed keywords

GERMANIUM COMPOUNDS; SELENIUM; SELENIUM COMPOUNDS; SYNTHESIS (CHEMICAL); TIN COMPOUNDS;

CUBANE COMPLEXES; DOUBLE BONDS; GERMANIUMS (GE); MAIN-GROUP ELEMENTS; MONOMERIC COMPLEXES; MULTIPLE BONDS; X-RAY STRUCTURE;

GERMANIUM;

CUBANE DERIVATIVE; GERMANIUM DERIVATIVE; SELENIUM DERIVATIVE; TIN DERIVATIVE;

ARTICLE; CHEMICAL BOND; COMPLEX FORMATION; CRYSTAL STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION; REACTION ANALYSIS; SEMICONDUCTOR; STRUCTURE ANALYSIS; TEMPERATURE DEPENDENCE;

EID: 0037833479     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejic.200300075     Document Type: Article

References (34)

1. II chalcogenides, see: [1a] S. Schlecht, M. Budde, L. Kienle, Inorg. Chem. 2002, 41, 6001. [1b] S. Schlecht, L. Kienle, Inorg. Chem. 2001, 40, 5719. [1c] Y. Li, Z. Wang, Y. Ding, Inorg. Chem. 1999, 38, 4737.
2. II chalcogenides, see: [1a] S. Schlecht, M. Budde, L. Kienle, Inorg. Chem. 2002, 41, 6001. [1b] S. Schlecht, L. Kienle, Inorg. Chem. 2001, 40, 5719. [1c] Y. Li, Z. Wang, Y. Ding, Inorg. Chem. 1999, 38, 4737.
3. II chalcogenides, see: [1a] S. Schlecht, M. Budde, L. Kienle, Inorg. Chem. 2002, 41, 6001. [1b] S. Schlecht, L. Kienle, Inorg. Chem. 2001, 40, 5719. [1c] Y. Li, Z. Wang, Y. Ding, Inorg. Chem. 1999, 38, 4737.
4. [2a] P. Boudjouk, M. P. Remington Jr., D. G. Grier, W. Triebold, B. R. Jarabek, Organometallics 1999, 18, 4534.
5. [2b] P. Boudjouk, D. J. Seidler, S. R. Bahr, G. J. McCarthy, Chem. Mater. 1994, 6, 2108.
6. A. L. Seligson, J. Arnold, J. Am. Chem. Soc. 1993, 115, 8214.
7. [4a] N. Tokitoh, R. Okazaki, in The Chemistry of Organic Germanium, Tin and Lead Compounds, Vol. 2, Part 1, (Ed.: Z. Rapoport), Wiley, Chichester, U. K., 2002, p. 843.
8. [4b] N. Tokitoh, R. Okazaki, Adv. Organomet. Chem. 2001, 47, 121-166.
9. [4c] R. Okazaki, N. Tokitoh, Acc. Chem. Res. 2000, 33, 625.
10. [4d] P. P. Power, Chem. Rev: 1999, 99, 3463-3502.
11. [5a] T. Matsumoto, N. Tokitoh, R. Okazaki, J. Am. Chem. Soc. 1999, 121, 8811.
12. [5b] M. Saito, N. Tokitoh, R. Okazaki, J. Am. Chem. Soc. 1997, 119, 11124.
13. [5c] N. Tokitoh, T. Matsumoto, R. Okazaki, J. Am. Chem. Soc. 1997, 119, 2337.
14. [6a] S. R. Foley, G. P. A. Yap, D. S. Richeson, J. Chem. Soc., Dalton Trans. 2000, 1663.
15. [6b] S. R. Foley, R. Bensimon, D. S. Richeson, J. Am. Chem. Soc. 1997, 119, 10359.
16. [6c] Y. Zhou, D. S. Richeson, J. Am. Chem. Soc. 1996, 118, 10850.
17. [6d] W-P. Leung, W-H. Kwok, L. T. C. Law, Z-Y. Zhou, T. C. W. Mak, Chem. Commun. 1996, 505.
18. [6e] M. C. Kuchta, G. Parkin, J. Chem. Soc., Chem. Commun. 1994, 1351.
19. [6f] M. C. Kuchta, G. Parkin, J. Am. Chem. Soc. 1994, 116, 8377.
20. [6g] M. Veith, S. Becker, V. Huch, Angew. Chem. Int. Ed. Engl. 1989, 28, 1237; Angew. Chem. 1989, 101, 1287.
21. [6g] M. Veith, S. Becker, V. Huch, Angew. Chem. Int. Ed. Engl. 1989, 28, 1237; Angew. Chem. 1989, 101, 1287.
22. T. Chivers, G. Schatte, Chem. Commun. 2001, 2264.
23. M. Veith, M. Grosser, Z. Naturforsch., Teil B 1982, 37, 1375.
24. 1 of 0.051.
25. 1 of 0.043.
26. 1 of 0.032.
27. M. Veith, W. Frank, Angew. Chem. Int. Ed. Engl. 1985, 24, 223; Angew. Chem. 1985, 97, 312.
28. M. Veith, W. Frank, Angew. Chem. Int. Ed. Engl. 1985, 24, 223; Angew. Chem. 1985, 97, 312.
29. L. M. Berreau, L. K. Woo, J. Am. Chem. Soc. 1995, 117, 1314.
30. 2 has been reported, but no synthetic or structural details were given. R. Fleischer, D, Stalke, Organometallics 1998, 17, 832.
31. An X-ray structural determination revealed d(Ge=Te) = 2.4240(4) Å, M. Parvez, private communication [cf. 2.398(1) and 2.466(1) Å for germatellurones containing three- and five-coordinate germanium, respectively].[5c,6c]
32. 1 = 0.036. The carbon atoms of the disordered toluene molecule were allowed isotropic displacement parameters. CCDC-198992 (1a), -198993 (1c), -198994 (2), -198995 (3) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12, Union Road, Cambridge CB2 1EZ, UK; fax: (internat.) +44-1223/336-033; or E-mail: deposit@ccdc.cam.ac.uk).
33. 4. D. R. Armstrong, F. Benevelli, A. D. Bond, N. Feeder, E. A. Harron, A. D. Hopkins, M. McPartlin, D. Moncrieff, D. Sáez, E. A. Quadrelli, A. D. Woods, D. S. Wright, Inorg. Chem. 2002, 41, 1492.
34. R. E. Allan, M. A. Beswick, N. L. Cromhout, M. A. Paver, P. R. Raithby, A. Steiner, M. Trevithick, D. S. Wright, Chem. Commun. 1996, 1501.