Multiple bonds between Sn and S: Synthesis and structural characterization of (CyNC((t)Bu)NCy)2Sn=S and [(CyNC(Me)NCy)2Sn(μ-S)]2

Journal of the American Chemical Society

Volumn 118, Issue 44, 1996, Pages 10850-10852

  Zhou, Yuanlin ^a   Richeson, Darrin S ^a  

^a UNIVERSITY OF OTTAWA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

METAL COMPLEX; TIN;

ARTICLE; CRYSTALLOGRAPHY; DRUG STRUCTURE;

EID: 0029818078     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja960350e     Document Type: Article

References (32)

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28. 2.
29. Selected bond distances (Å) and bond angles (deg) for 2: Sn1-N1, 2.363(5); Sn1-N2, 2.203(5); Sn1-N3, 2.394(5); Sn1-N4, 2.186(5); N1-C1, 1.478(8); N1-C25, 1.327(8); N2-C7, 1.460(8); N2-C25, 1.329-(8); N3-C13, 1.444(8); N3-C30, 1.341(8); N4-C19, 1.448(8); N4-C30, 1.368(8); N1-Sn1-N2, 57.1(2); N1-C25-N2, 110.9(5); N1-Sn1-N3, 144.3(3); N1-C25-C26, 126.0(6); N1-Sn1-N4, 98.3(2); N2-C25-C26, 122.9(6); N2-Sn1-N3, 96.1(2); N4-C19-C20, 110.3(5); N2-Sn1-N4, 95.0(2); N4-C19-C24, 110.6(5); N3-Sn1-N4, 57.7(2); N3-C30-N4, 110.0(5); N3-C30-C31, 128.7(6); Sn1-N1-C1, 124.9(4); N4-C30-C31, 121.3(6); Sn1-N1-C25, 92.0(4); C1-N1-C25, 127.0(5); Sn1-N2-C7, 133.7(4); Sn1-N2-C25, 99.3(4); C7-N2-C25, 127.0(5); Sn1-N3-C13, 130.0(4); Sn1-N3-C30, 91.1(4); C13-N3-C30, 128.5(5); Sn1-N4-C19, 130.9(4); Sn1-N4-C30, 99.7(4); C19-N4-C30, 129.5(5); N2-C7-C12, 110.3(5).
30. -], see: Kilimann, U.; Noltemeyer, M.; Edelmann, F. T. J. Organomet. Chem. 1993, 443, 35.
31. Selected bond distances (Å) and bond angles (deg) for 3: Sn1-N1, 2.19(1); Sn1-N2, 2.09(1); N1-C1, 1.47(2); N1-C5, 1.69(2); N2-C5, 1.70(2); S1-Sn1-N1, 107.9(3); S1-Sn1-N2, 130.0(3); N1-Sn1-N1a, 144.2(4); N1-Sn1-N2, 78.6(2); N2-Sn1-N2b, 100.0(5); N2-C10-C11, 108.1(13); Sn1-N1-C1, 136.1(8); C5-N2-C10c, 113.0(11); Sn1-N1-C5, 85.5(7); N1-C5-C6, 129.0(13); C1-N1-C5, 115.1(7); C5-C6-C8, 105.9(14); Sn1-N2-C5, 88.5(8); Sn1-N2-C10, 157.5(7); N1-C5-N2, 106.4(11); N2-C5-C6, 122.7(14); C5-C6-C7, 115.3(15).
32. Selected bond distances (Å) and bond angles (deg) for 4: Sn1-N1, 2.226(5); N1-C1, 1.456(7); Sn1-N2, 2.264(4); N1-C13, 1.315(7); Sn1-N3, 2.215(4); N2-C7, 1.475(7); Sn1-N4, 2.226(4); N2-C13, 1.345-(8); S1-Sn1a, 2.4757(16); N3-C15, 1.466(8); N4-C21, 1.466(7); N3-C27, 1.322(8); N4-C27, 1.305(7); S1-Sn1-S1a, 88.95(5); N2-Sn1-N3, 143.1(2); S1-Sn1-N1, 157.1(1); N2-Sn1-N4, 93.17(2); S1-Sn1-N2, 98.6(1); N3-Sn1-N4, 59.1(2); S1-Sn1-N3, 107.9(1); Sn1-S1-Sn1a, 89.24(5); S1-Sn1-N4, 97.1(1); C1-N1-C13, 123.9(5); S1a-Sn1-N1, 93.6(1); Sn1-N2-C13, 92.7(3); S1a-Sn1-N2, 108.4(1); C7-N2-C13, 121.3(4); S1a-Sn1-N3, 97.6(1); Sn1-N3-C27, 94.0(3); S1a-Sn1-N4, 156.6(1); C15-N3-C27, 124.2(5); N1-Sn1-N2, 59.1(2); Sn1-N4-C27, 94.0(4); N1-Sn1-N3, 94.3(2); C21-N4-C27, 124.1(5).