Spectroscopic, computational, and kinetic studies of the μ4-sulfide-bridged tetranuclear CuZ cluster in N 2O reductase: pH effect on the edge ligand and its contribution to reactivity

Journal of the American Chemical Society

Volumn 129, Issue 13, 2007, Pages 3955-3965

  Ghosh, Somdatta ^a   Gorelsky, Serge I ^a   George, Serena DeBeer ^b   Chan, Jeannine M ^c   Cabrito, Inês ^d   Dooley, David M ^c   Moura, José J G ^d   Moura, Isabel ^d   Solomon, Edward I ^a  

^a STANFORD UNIVERSITY   (United States)

^b SLAC NATIONAL ACCELERATOR LABORATORY   (United States)

^c MONTANA STATE UNIVERSITY   (United States)

^d DEPARTAMENTO DE QUÍMICA   (Portugal)

Author keywords

[No Author keywords available]

Indexed keywords

COPPER COMPOUNDS; DICHROISM; NITROGEN OXIDES; PARAMAGNETIC RESONANCE; PH EFFECTS; REACTION KINETICS; SPECTROSCOPIC ANALYSIS;

KINETIC STUDIES; MAGNETIC CIRCULAR DICHROISM;

DENSITY FUNCTIONAL THEORY;

COPPER DERIVATIVE; NITROUS OXIDE REDUCTASE; SULFIDE;

ABSORPTION; ARTICLE; CALCULATION; CIRCULAR DICHROISM; DENSITY FUNCTIONAL THEORY; ELECTRON SPIN RESONANCE; ENZYME KINETICS; HYDROGEN BOND; LIGAND BINDING; PH MEASUREMENT; PROTON TRANSPORT; PSEUDOMONAS; PSEUDOMONAS NAUTICA; REACTION ANALYSIS; SPECTROSCOPY; VIBRATION;

COMPUTER SIMULATION; COPPER; CROSS-LINKING REAGENTS; CRYSTALLOGRAPHY, X-RAY; ELECTRON SPIN RESONANCE SPECTROSCOPY; HYDROGEN-ION CONCENTRATION; KINETICS; LIGANDS; MODELS, MOLECULAR; MOLECULAR CONFORMATION; OXIDOREDUCTASES; SULFIDES; VIBRATION;

EID: 34247140223     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja068059e     Document Type: Article

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