Reactions of Hydrogen or Deuterium Molecule with a Rhodium(II) Metalloradical: Kinetic Evidence for a Four-Centered Transition State

Inorganic Chemistry

Volumn 31, Issue 1, 1992, Pages 148-150

  Wayland, Bradford B ^a   Ba, Sujuan ^a   Sherry, Alan E ^a  

^a UNIVERSITY OF PENNSYLVANIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000819864     PISSN: 00201669     EISSN: 1520510X     Source Type: Journal    
DOI: 10.1021/ic00027a031     Document Type: Article

References (47)

1. James, B. R. Comprehensive Organometallic Chemistry; Wilkinson, G., Stone, F. G. A., Abel, E. W., Eds.; Pergamon: New York, 1982; Vol. 8, p 285.
2. Jardine, F. H. Prog. Inorg. Chem. 1981, 28, 63.
3. Faller, J. W. Homogeneous Catalysis with Metal Phosphine Complexes; Pignolet, L. H., Ed.; Plenum: New York, 1983; Chapter 2.
4. Collman, J. P.; Hegedus, L. S.; Norton, J. R.; Finke, R. G. Principles and Applications of Organotransition Metal Chemistry; University Science Books: Mill Valley, CA, 1987; p 286.
5. Chock, P. B.; Halpern, J. J. Am. Chem. Soc. 1966, 88, 3511.
6. Zhou, P.; Vitale, A. A.; San Filippo, J., Jr.; Saunders, W. H., Jr. J. Am. Chem. Soc. 1985, 107, 8049.
7. Johnson, C. E.; Eisenberg, R. J. Am. Chem. Soc. 1985, 107, 6531.
8. Kunin, A. J.; Farid, R.; Johnson, C. E.; Eisenberg, R. J. Am. Chem. Soc. 1985, 107, 5315.
9. Wink, D.; Ford, P. C. J. Am. Chem. Soc. 1985, 107, 1794.
10. Kubas, G. J.; Ryan, R. R.; Swanson, B. I.; Vergamini, P. J.; Wasserman, H. J. J. Am. Chem. Soc. 1984, 106, 451.
11. Morris, R. H.; Sawyer, J. F.; Shiralain, M.; Zubkowski, J. D. J. Am. Chem. Soc. 1985, 107, 5581.
12. Crabtree, R. H.; Lavin, M. J. Chem. Soc., Chem. Commun. 1985, 794.
13. Sweany, R. L. Organometallics 1986, 5, 387.
14. Collman, J. P.; Wagenknecht, P. S.; Hembre, R. T.; Lewis, N. S. J. Am. Chem. Soc. 1990, 112, 1294.
15. Collman, J. P.; Hutchison, J. E.; Wagenknecht, P. S.; Lewis, N. S.; Lopez, M. A.; Guilard, R. J. Am. Chem. Soc. 1990, 112, 8206.
16. Sailliard, J.-Y.; Hoffman, R. J. Am. Chem. Soc. 1984, 106, 2006.
17. Nakatsuji, H.; Hada, M. J. Am. Chem. Soc. 1985, 107, 8264.
18. Siegbahn, P. E. M.; Blomberg, M. R. A.; Bauslicher, C. W., Jr. J. Chem. Phys. 1984, 81, 1373.
19. Low, J. J.; Goddard, W. A., III. J. Am. Chem. Soc. 1984, 106, 8321.
20. Obara, S.; Kitaura, K.; Morkuma, K. J. Am. Chem. Soc. 1984, 106, 7482.
21. Brothers, P. J. Prog. Inorg. Chem. 1980, 28, 1.
22. Fachinett, G.; Del Cima, F.; Braca, G. F.; Funaioli, T. J. Organomet. Chem. 1984, 275, C25.
23. Sisak, A.; Ungvary, F.; Marko, L. Organometallics 1983, 2, 1244.
24. Halpern, J.; Pribanic, M. Inorg. Chem. 1970, 9, 2616.
25. Halpern, J. Inorg. Chim. Acta 1983, 77, L105.
26. Halpern, J. Inorg. Chim. Acta 1982, 62, 31.
27. Simandi, L. I.; Budo-Zahony, E.; Szvernyi, Z.; Memeth, S. J. Chem. Soc., Dalton Trans. 1980, 276.
28. Chao, T.-H.; Espenson, J. H. J. Am. Chem. Soc. 1978, 100, 129.
29. Sherry, A. E.; Wayland, B. B. J. Am. Chem. Soc. 1990, 112, 1259.
30. Wayland, B. B.: Ba, S.; Sherry, A. E. J. Am. Chem. Soc. 1991, 113, 5305.
31. Sullivan, J. H. J. Chem. Phys. 1967, 46, 73.
32. Bigeleisen, J.; Klein, F. S.; Weston, R. E.; Wolfsberg, M. J. Chem. Phys. 1959, 30, 1340.
33. Carmichael, H.; Johnston, H. S. J. Chem. Phys. 1964, 41, 1975.
34. Persky, A. Z.; Klein, F. S. J. Chem. Phys. 1966, 44, 3617.
35. Johnston, H. S. Adv. Chem. Phys. 1960, 3, 131.
36. Johnston, H. S. Gas Phase Reaction Rate Theory, The Ronald Press Co.: New York, 1966; pp 239-251.
37. Porter, R. N.; Karplus, M. J. Chem. Phys. 1964, 40, 1105.
38. Wayland, B. B.; Coffin, V. L.; Farnos, M. D. Inorg. Chem. 1988, 27, 2745.
39. Wayland, B. B. Polyhedron 1988, 7, 1545.
40. Ozaki, A. Isotope Studies in Heterogeneous Catalysis; Academic Press: New York, 1976; p 172.
41. Wink, D. A.; Ford, P. C. J. Am. Chem. Soc. 1987, 109, 436.
42. Melander, L.; Saunders, W. H. Reaction Rates of Isotopie Molecules; Wiley-Interscience: New York, 1980.
43. Lowry, T. H.; Richardson, K. S. Mechanism and Theory in Organic Chemistry, Third ed.; Harper & Row: New York, 1987.
44. Hertzberg, G. Spectra of Diatomic Moleculars, Second Ed.; D. Van Nostrand Co.: New York, 1963.
45. Stoutland, P. O.; Bergman, R. G. J. Am. Chem. Soc. 1988, 110, 5732.
46. Jones, W. D.; Feher, F. J. J. Am. Chem. Soc. 1986, 108, 4814.
47. Chiltz, G.; Eckling, R.; Goidfinger, P.; Huybrechts, G.; Johnston, H. S.; Meyers, L.; Verbeke, G. J. Chem. Phys. 1963, 38, 1053.