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Volumn 349, Issue 17-18, 2007, Pages 2603-2609

Study of the efficiency of amino-functionalized ruthenium and ruthenacycle complexes as racemization catalysts in the dynamic kinetic resolution of 1-phenylethanol

Author keywords

Chiral alcohols; Dynamic kinetic resolution; Ligand assistance; Racemization; Ruthenium; Transfer hydrogenation

Indexed keywords


EID: 37349051372     PISSN: 16154150     EISSN: 15213897     Source Type: Journal    
DOI: 10.1002/adsc.200700379     Document Type: Article
Times cited : (22)

References (38)
  • 10
  • 37
    • 0000543551 scopus 로고    scopus 로고
    • It is well known that 1,3-oxazolidines exist as mixtures of ring-chain tautomers: F. Fülöp, K. Pihlaja, K. Neuvonen, G. Bernáth, G. Argay, A. Kálmán, J. Org. Chem. 1993, 58, 1967-1969. With IR and NMR it could be observed in our case that 9b consists for 12% in the open-chain form. The 2-H (ring form, 5 ppm) and the corresponding CH=N (open-chain form, 8.3 ppm) were used for integration. 8a mainy exists in the ring form.
    • It is well known that 1,3-oxazolidines exist as mixtures of ring-chain tautomers: F. Fülöp, K. Pihlaja, K. Neuvonen, G. Bernáth, G. Argay, A. Kálmán, J. Org. Chem. 1993, 58, 1967-1969. With IR and NMR it could be observed in our case that 9b consists for 12% in the open-chain form. The 2-H (ring form, 5 ppm) and the corresponding CH=N (open-chain form, 8.3 ppm) were used for integration. 8a mainy exists in the ring form.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.