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It is well known that 1,3-oxazolidines exist as mixtures of ring-chain tautomers: F. Fülöp, K. Pihlaja, K. Neuvonen, G. Bernáth, G. Argay, A. Kálmán, J. Org. Chem. 1993, 58, 1967-1969. With IR and NMR it could be observed in our case that 9b consists for 12% in the open-chain form. The 2-H (ring form, 5 ppm) and the corresponding CH=N (open-chain form, 8.3 ppm) were used for integration. 8a mainy exists in the ring form.
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