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Whereas the catecholborane (HBcat) has traditionally been employed in such hydroboration reactivity surveys, HBpin was chosen specifically for the studies herein because HBpin is significantly more stable to air and nucleophiles than is HBcat, and the greater steric bulk of HBpin provides an increased challenge in terms of attaining branched selectivity. For further details, see: (a) Crudden, C. M.; Hleba, Y. B.; Chen, A. C. J. Am. Chem. Soc. 2004, 126, 9200.
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Whereas the catecholborane (HBcat) has traditionally been employed in such hydroboration reactivity surveys, HBpin was chosen specifically for the studies herein because HBpin is significantly more stable to air and nucleophiles than is HBcat, and the greater steric bulk of HBpin provides an increased challenge in terms of attaining branched selectivity. For further details, see: (a) Crudden, C. M.; Hleba, Y. B.; Chen, A. C. J. Am. Chem. Soc. 2004, 126, 9200.
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