Enantioselective allylic substitution of cyclic substrates by catalysis with palladium complexes of P,N-chelate ligands with a cymantrene unit

Angewandte Chemie - International Edition

Volumn 37, Issue 21, 1998, Pages 3047-3050

  Kudis, Steffen ^a   Helmchen, Günter ^a  

^a UNIVERSITY OF HEIDELBERG   (Germany)

Author keywords

Allyl complexes; Asymmetric catalysis; Ligand effects; N ligands; P ligands; Palladium

Indexed keywords

CYMANTRENE; LIGAND; MANGANESE DERIVATIVE; NITROGEN; PALLADIUM COMPLEX; PHOSPHORUS; TRICARBONYLCYCLOPENTADIENYLMANGANESE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHROMATOGRAPHY; COMPLEX FORMATION; CRYSTAL STRUCTURE; NUCLEAR OVERHAUSER EFFECT; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE;

EID: 0032538768     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19981116)37:21<3047::AID-ANIE3047>3.0.CO;2-J     Document Type: Article

References (24)

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23. 2 for all observed reflexes; program used: SHELXTL (G. M. Sheldrick, Universität Go̊ttingen). Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-101206. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB21EZ, UK (fax: (+44)1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).
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