Synthesis and crystallographic characterization of new manganese(I) complexes of donor-functionalized indenes

Organometallics

Volumn 24, Issue 7, 2005, Pages 1737-1746

  Cipot, Judy ^a   Wechsler, Dominik ^a   McDonald, Robert ^b   Ferguson, Michael J ^b   Stradiotto, Mark ^a  

^a DALHOUSIE UNIVERSITY   (Canada)

^b UNIVERSITY OF ALBERTA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

COMPLEXATION; CRYSTALLOGRAPHY; NUCLEAR MAGNETIC RESONANCE; ORGANIC SOLVENTS; SPECTRUM ANALYSIS; SYNTHESIS (CHEMICAL); TOLUENE; X RAY ANALYSIS;

INDENES; LIGANDS; METAL FRAGMENTS; REACTION MIXTURES;

MANGANESE COMPOUNDS;

EID: 16244387698     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0490435     Document Type: Article

References (43)

1. (a) Stradiotto, M.; Cipot, J.; McDonald, R. J. Am. Chem. Soc. 2003, 125, 5618.
2. (b) Cipot, J.; Wechsler, D.; Stradiotto, M.; McDonald, R.; Ferguson, M. J. Organometallics 2003, 22, 5185.
3. Wechsler, D.; McDonald, R.; Ferguson, M. J.; Stradiotto, M. Chem. Commun. 2004, 2446.
4. Pearson, R. G. Inorg. Chem. 1988, 27, 734.
5. Wheatley, N.; Kalck, P. Chem. Rev. 1999, 99, 3379.
6. (a) Schubert, U.; Soholz, G.; Müller, J.; Ackermann, K.; Wörle, B.; Stansfield, R. F. D. J. Organomet. Chem. 1986, 306, 303.
7. (b) King, W. A.; Luo, X.-L.; Scott, B. L.; Kubas, G. J.; Zum, K. W. J. Am. Chem. Soc. 1996, 118, 6782.
8. (c) Toupadakis, A.; Kubas, G. J.; King, W. A.; Scott, B. L.; Huhmann-Vincent, J. Organometallics 1998, 17, 5315, and references therein.
9. (d) Schlecht, S.; Hartwig, J. F. J. Am. Chem. Soc. 2000, 122, 9435, and references therein.
10. For selected studies involving structurally related cationic and formally zwitterionic Mn(I) complexes, see: (a) Ruiz, J.; Riera, V.; Vivanco, M.; García-Granda, S.; Garća-Fernández, A. Organometallics 1992, 11, 4077.
11. For selected studies involving structurally related cationic and formally zwitterionic Mn(I) complexes, see: (a) Ruiz, J.; Riera, V.; Vivanco, M.; García-Granda, S.; Garća-Fernández, A. Organometallics 1992, 11, 4077. (b) Ruiz, J.; Riera, V.; Vivanco, M.; García-Granda, S.; Salvadó, M. A. Organometallics 1996, 25, 1079. (c) Ruiz, J.; Riera, V.; Vivanco, M.; Lanfranchi, M.; Tiripicchio, A. Organometallics 1998, 17, 3835. (d) Quesada, R.; Ruiz, J.; Riera, V.; García-Granda, S.; Díaz, M. R. Chem. Commun. 2003, 1942.
12. For selected studies involving structurally related cationic and formally zwitterionic Mn(I) complexes, see: (a) Ruiz, J.; Riera, V.; Vivanco, M.; García-Granda, S.; Garća-Fernández, A. Organometallics 1992, 11, 4077. (b) Ruiz, J.; Riera, V.; Vivanco, M.; García-Granda, S.; Salvadó, M. A. Organometallics 1996, 25, 1079. (c) Ruiz, J.; Riera, V.; Vivanco, M.; Lanfranchi, M.; Tiripicchio, A. Organometallics 1998, 17, 3835. (d) Quesada, R.; Ruiz, J.; Riera, V.; García-Granda, S.; Díaz, M. R. Chem. Commun. 2003, 1942.
13. For selected studies involving structurally related cationic and formally zwitterionic Mn(I) complexes, see: (a) Ruiz, J.; Riera, V.; Vivanco, M.; García-Granda, S.; Garća-Fernández, A. Organometallics 1992, 11, 4077. (b) Ruiz, J.; Riera, V.; Vivanco, M.; García-Granda, S.; Salvadó, M. A. Organometallics 1996, 25, 1079. (c) Ruiz, J.; Riera, V.; Vivanco, M.; Lanfranchi, M.; Tiripicchio, A. Organometallics 1998, 17, 3835. (d) Quesada, R.; Ruiz, J.; Riera, V.; García-Granda, S.; Díaz, M. R. Chem. Commun. 2003, 1942.
14. Wong, W.-Y.; Wong, W.-K.; Sun, C.; Wong, W.-T. J. Organomet. Chem. 2000, 612, 160.
15. (a) Nitschke, J.; Schmidt, S. P.; Trogler, W. C. Inorg. Chem. 1985, 24, 1972.
16. (b) Beck, W.; Sünkel, K. Chem. Rev. 1988, 88, 1405, and references therein.
17. (c) Schweiger, M.; Beck, W. Z. Anorg. Allg. Chem. 1991, 595, 203.
18. Becker, T. M.; Krause Bauer, J. A.; Del Bene, J. E.; Orchin, M. J. Organomet. Chem. 2001, 629, 165.
19. 3 complexes, see: (a) Tomlinson, A. A. G.; Bonamico, M.; Dessy, G.; Fares, V.; Scaramuzza, L. J. Chem. Soc., Dalton Trans. 1972, 1671. (b) Olgemöller, B.; Bauer, H.; Löbermann, H.; Nagel, U.; Beck, W. Chem. Ber. 1982, 115, 2271. (c) Rheingold, A. L.; Wu, G.; Heck, R. F. Inorg. Chim. Acta 1987, 131, 147. (d) Rybtchinski, B.; Oevers, S.; Montag, M.; Vigalok, A.; Rozenberg, H.; Martin, J. M. L.; Milstein, D. J. Am. Chem. Soc. 2001, 123, 9064.
20. 3 complexes, see: (a) Tomlinson, A. A. G.; Bonamico, M.; Dessy, G.; Fares, V.; Scaramuzza, L. J. Chem. Soc., Dalton Trans. 1972, 1671. (b) Olgemöller, B.; Bauer, H.; Löbermann, H.; Nagel, U.; Beck, W. Chem. Ber. 1982, 115, 2271. (c) Rheingold, A. L.; Wu, G.; Heck, R. F. Inorg. Chim. Acta 1987, 131, 147. (d) Rybtchinski, B.; Oevers, S.; Montag, M.; Vigalok, A.; Rozenberg, H.; Martin, J. M. L.; Milstein, D. J. Am. Chem. Soc. 2001, 123, 9064.
21. 3 complexes, see: (a) Tomlinson, A. A. G.; Bonamico, M.; Dessy, G.; Fares, V.; Scaramuzza, L. J. Chem. Soc., Dalton Trans. 1972, 1671. (b) Olgemöller, B.; Bauer, H.; Löbermann, H.; Nagel, U.; Beck, W. Chem. Ber. 1982, 115, 2271. (c) Rheingold, A. L.; Wu, G.; Heck, R. F. Inorg. Chim. Acta 1987, 131, 147. (d) Rybtchinski, B.; Oevers, S.; Montag, M.; Vigalok, A.; Rozenberg, H.; Martin, J. M. L.; Milstein, D. J. Am. Chem. Soc. 2001, 123, 9064.
22. 3 complexes, see: (a) Tomlinson, A. A. G.; Bonamico, M.; Dessy, G.; Fares, V.; Scaramuzza, L. J. Chem. Soc., Dalton Trans. 1972, 1671. (b) Olgemöller, B.; Bauer, H.; Löbermann, H.; Nagel, U.; Beck, W. Chem. Ber. 1982, 115, 2271. (c) Rheingold, A. L.; Wu, G.; Heck, R. F. Inorg. Chim. Acta 1987, 131, 147. (d) Rybtchinski, B.; Oevers, S.; Montag, M.; Vigalok, A.; Rozenberg, H.; Martin, J. M. L.; Milstein, D. J. Am. Chem. Soc. 2001, 123, 9064.
23. A recently reported PCN-based Rh(III) pincer complex features a coordinated (and fluxional) tetrafluoroborate anion that is displaced by THF at reduced temperatures: Gandelman, M.; Konstantinovski, L.; Rozenberg, H.; Milstein, D. Chem. Eur. J. 2003, 9, 2595.
24. Abney, K. D.; Long, K. M.; Anderson, O. F.; Strauss, S. H. Inorg. Chem. 1987, 26, 2638.
25. Ault, B. S.; Becker, T. M.; Li, G. Q.; Orchin, M. Spectrochim. Acta A 2004, 60, 2567.
26. (a) Kudis, S.; Helmchen, G. Angew. Chem., Int. Ed. 1998, 37, 3047.
27. (b) Son, S. U. K.; Park, K. H.; Lee, S. L.; Chung, Y. K.; Sweigart, D. A. Chem. Commun. 2001, 1290.
28. (c) Delacroix, O.; Gladysz, J. A. Chem. Commun. 2003, 665.
29. (d) Lee, J. H.; Son, S. U.; Chung, Y. K. Tetrahedron: Asymmetry 2003, 14, 2109.
30. (a) Plenio, H.; Burth, D. Organometallics 1996, 15, 1151.
31. (b) Plenio, H.; Burth, D. Z. Anorg. Allg. Chem. 1996, 622, 225.
32. 5-indenyl complexes, see: Greidanus, G.; McDonald, R.; Stryker, J. M. Organometallics 2001, 20, 2492, and references therein.
33. Iggo, J. A.; Mays, M. J.; Raithby, P. R.; Henrick, K. J. Chem. Soc., Dalton Trans. 1984, 633.
34. 5-mdenyl complexes, see: Starzewski, K. A. O.; Kelly, W. M.; Stumpf, A.; Freitag, D. Angew. Chem., Int. Ed. 1999, 38, 2439.
35. For example: Stradiotto, M.; Hazendonk, P.; Bain, A. D.; Brook, M. A.; McGlinchey, M. J. Organometallics 2000, 19, 590, and references therein.
36. For the lithiation of substituted cymantrenes, see: Ginzburg, A. G. Russ. Chem. Rev. 1993, 62, 1025.
37. For the crystal structure of meso-1,1′-biindenyl, see: Lustenberger, P.; Joss, S.; Engel, P.; Oesch, N.; Rutsch, W.; Neuenschwander, M. Z. Kristallogr. 1979, 150, 235.
38. For example: Huber, T. A.; Bélanger-Gariépy, F.; Zargarian, D. Organometallics 1995, 14, 4997.
39. Barsties, E.; Schaible, S.; Prosenc, M.-H.; Rief, U.; Röll, W.; Weyland, O.; Dorer, B.; Brintzinger, H.-H. J. Organomet. Chem. 1996, 520, 63.
40. ORTEP-3 for Windows: Farrugia, L. J. J. Appl. Crystallogr. 1997, 30, 565.
41. (a) Naumann, K.; Zon, G.; Mislow, K. J. Am. Chem. Soc. 1969, 91, 7012.
42. (b) Zon, G.; DeBruin, K. E.; Naumann, K.; Mislow, K. J. Am. Chem. Soc. 1969, 91, 7023.
43. Gilbertson, S. R.; Xie, D.; Fu, Z. J. Org. Chem. 2001, 66, 7240.