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Volumn , Issue 33, 2007, Pages 5492-5495

Organocatalytic asymmetric β-hydroxylation of α,β- unsaturated ketones

Author keywords

Asymmetric catalysis; Conjugate addition; Ketones; Organocatalysis; Oximes

Indexed keywords


EID: 36349020257     PISSN: 1434193X     EISSN: 10990690     Source Type: Journal    
DOI: 10.1002/ejoc.200700873     Document Type: Article
Times cited : (64)

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    • In the absence of an acidic counteranion, the 9-amino9-deoxy, epi-hydroquinine is not able to promote the oxa-Michael addition. This result excludes a possible base-catalyzed processes proceeding through the activation of the oxime by hydrogen bonding to the basic quinuclidine nitrogen atom. For this type of activation of oximes in asymmetric organocatalytic Michael additions, see ref.[13d
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.