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Volumn 129, Issue 14, 2007, Pages 4124-4125

Organocatalysis in radical chemistry. Enantioselective α-oxyamination of aldehydes

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDE DERIVATIVE;

EID: 34247165162     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja069245n     Document Type: Article
Times cited : (265)

References (41)
  • 1
    • 84955394357 scopus 로고    scopus 로고
    • Yamamoto, H, Ed, Wiley-VCH: New York, Vols, and 2
    • Lewis Acids in Organic Synthesis; Yamamoto, H., Ed.; Wiley-VCH: New York, 2000; Vols. 1 and 2.
    • (2000) Lewis Acids in Organic Synthesis , vol.1
  • 15
    • 0041733541 scopus 로고    scopus 로고
    • For the use of organocatalysis in α-functionalization of carbonyl compounds: aldehydes, a
    • For the use of organocatalysis in α-functionalization of carbonyl compounds: (aldehydes) (a) Brown, S. P.; Brochu, M. P.; Sinz, C. J.; MacMillan, D. W. C. J. Am. Chem. Soc. 2003, 125, 10808.
    • (2003) J. Am. Chem. Soc , vol.125 , pp. 10808
    • Brown, S.P.1    Brochu, M.P.2    Sinz, C.J.3    MacMillan, D.W.C.4
  • 32
    • 1842603677 scopus 로고    scopus 로고
    • For reviews on α-hetero functionalization of carbonyl compounds see: a
    • For reviews on α-hetero functionalization of carbonyl compounds see: (a) Chen, B.-C.; Zhou, P.; Davis, F. A.; Ciganek, E. Org. React. 2003, 62, 1.
    • (2003) Org. React , vol.62 , pp. 1
    • Chen, B.-C.1    Zhou, P.2    Davis, F.A.3    Ciganek, E.4
  • 36
    • 34247148119 scopus 로고    scopus 로고
    • For details on reaction conditions and workup see Supporting Information
    • For details on reaction conditions and workup see Supporting Information.
  • 39
    • 34247104623 scopus 로고    scopus 로고
    • We have screened a large number of organocatalysts in an effort to improve selectivity. Of these, compound 10b was optimal
    • We have screened a large number of organocatalysts in an effort to improve selectivity. Of these, compound 10b was optimal.
  • 40
    • 34247093847 scopus 로고    scopus 로고
    • Reaction with cyclohexanone gave the oxygenated product as a racemate in 86% yield
    • Reaction with cyclohexanone gave the oxygenated product as a racemate in 86% yield.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.