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Volumn 46, Issue 22, 2007, Pages 9139-9145

Luminescent iridium phenanthroline crown ether complex for the detection of silver(I) ions in aqueous media

Author keywords

[No Author keywords available]

Indexed keywords

CROWN ETHER; DIVALENT CATION; IRIDIUM; PHENANTHROLINE DERIVATIVE; SILVER; WATER;

EID: 35848937580     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic700413v     Document Type: Article
Times cited : (214)

References (63)
  • 23
    • 4344562115 scopus 로고    scopus 로고
    • (e) Richter, M. M. Chem. Rev. 2004, 104, 3003-3036.
    • (2004) Chem. Rev , vol.104 , pp. 3003-3036
    • Richter, M.M.1
  • 38
    • 13644252174 scopus 로고    scopus 로고
    • The reduction of ppy ligand is at more cathodic potential. See
    • The reduction of ppy ligand is at more cathodic potential. See Kim, J. I.; Shin, I.-S.; Kim, H.; Lee, J.-K. J. Am. Chem. Soc. 2005, 127, 1614-1615.
    • (2005) J. Am. Chem. Soc , vol.127 , pp. 1614-1615
    • Kim, J.I.1    Shin, I.-S.2    Kim, H.3    Lee, J.-K.4
  • 58
    • 35848962152 scopus 로고    scopus 로고
    • This statement is consistently corroborated by a number of observations and reasonings: (i) We observe identical spectral shape and similar emission energy for the Ag+-bound 1 and parent complex 3, ii) 3-MLCT emissions are known for their broad and featureless spectrum, iii) While 1 shows a temperature-independent emission wavelength, the silver-loaded complex displays a strong temperature dependence see Supporting Information Figures S12 and S13, Apparently, larger loadings of metal ions change the character of the emission of 1 from 3LC to 3MLCT because ligand 7 becomes increasingly a better acceptor
    • 3MLCT because ligand 7 becomes increasingly a better acceptor.
  • 59
    • 35848931321 scopus 로고    scopus 로고
    • Association constants were obtained using the computer program SPECFIT, Global Analysis system, Version 3.0.32
    • (a) Association constants were obtained using the computer program SPECFIT, Global Analysis system, Version 3.0.32.
  • 61
    • 35848957123 scopus 로고    scopus 로고
    • 2+) on one molecule of 1.
    • 2+) on one molecule of 1.
  • 63
    • 0004201208 scopus 로고
    • Ellis Horwood: Chichester, U.K
    • Hay, R. W. Bio-inorganic Chemistry; Ellis Horwood: Chichester, U.K., 1984; p 10.
    • (1984) Bio-inorganic Chemistry , pp. 10
    • Hay, R.W.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.