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Eu3(AsS4)2: It was prepared by combining Eu (0.091g, 0.6mmol, As (0.03g, 0.4mmol, and S (0.051g, 1.6mmol, The starting materials were loaded in a fused-silica tube in a nitrogen-filled glove box. The tube was evacuated (<10-4 Torr) and sealed, put in a computer-controlled furnace, and heated to 650°C in 10 h. It was maintained at this temperature for 60 h, followed by cooling at the rate of 5°C/h to room temperature. The product consisted of dark-red chunks. Semi-quantitative microprobe analysis using energy dispersive spectroscopy (EDS) on the dark-red chunks gave Eu3.4As2S7.2. Li0.73Eu3As4.43S10: This compound was isolated from the reaction mixture of Li2S (0.015g, 0.33mmol, Eu (0.101g, 0.67mmol, As (0.125g, 1.67mmol, and S (0.075g, 2.33mmol) using a similar procedure as above. The product was isolated by washing with dime
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10.4".
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35649025933
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Eu3(AsS4)2: A full sphere of data was collected on a red crystal using a Bruker AXS SMART diffractometer. An empirical absorption correction was applied using SADABS. The structure was solved with direct methods using the SHELXTL package. Hexagonal R3c, a, 9.254(3) Å, b, 9.254(3) Å, c, 27.698(12) Å, Dc, 4.182 g/cm3, crystal dimensions: 0.15 x 0.10 x 0.03 mm3, θ, 2.94-28.26°, μ, 19.540 mm -1, 1834 total reflections, 541 unique reflections with R int, 0.027, GOF, 1.008, R1, 2.38, wR2, 5.80% for I > 2σ(I, Li0.73Eu3As4.43S 10 (IIa, Single-crystal X-ray diffraction data were collected using a STOE imaging plate diffraction system (IPDS-2) with graphite- monochromatized Mo Kα radiation. A numerical absorption correction was applied usi
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int = 0.0730, GOF = 1.088, R1 = 4.49%, wR2 = 9.81% for I > 2σ(I).
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0012474658
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Berlepsch, P.1
Armbruster, T.2
Topa, D.3
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0037297306
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Armbruster, T.2
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Topa, D.4
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Work to characterize these members is under way
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Work to characterize these members is under way.
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