K3Ln(AsS4)2 (Ln = Nd, Sm, Gd): The first rare earth thioarsenate compounds with infinite straight ∞ 1[Ln(AsS4)2]3- chains

Inorganic Chemistry

Volumn 45, Issue 22, 2006, Pages 8835-8837

  Wu, Yuandong ^a   Näther, Christian ^a   Bensch, Wolfgang ^a  

^a UNIVERSITY OF KIEL   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33751410818     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic060933h     Document Type: Article

References (35)

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30. 2 (Ln = Nd, Sm, Gd) (50-60%) were isolated by washing away the excessive flux with N,N-dimethylformamide. Energy-dispersive X-ray analyses (EDX) on a number of crystals indicated the presence of K, Ln, As, S in an ∼3:1:2:8 molar ratio.
31. 2) = 0.0823, GOF = 0.974.
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34. 4 was used as a standard for 100% reflectance.
35. -1.