Interwoven pair of open frameworks in the thiosphosphate K 6Yb3(PS4)5

Journal of the American Chemical Society

Volumn 126, Issue 38, 2004, Pages 11780-11781

  Aitken, Jennifer A ^a   Kanatzidis, Mercouri G ^a  

^a MICHIGAN STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKALI METAL; CHALCOPHOSPHATE; LANTHANIDE; PHOSPHATE; POTASSIUM THIOPHOSPHATE; UNCLASSIFIED DRUG; YTTERBIUM;

ARTICLE; CRYSTALLOGRAPHY; GEOMETRY; MAGNETIC FIELD; MATERIALS; STRUCTURE ANALYSIS;

EID: 4644357721     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0474648     Document Type: Article

References (37)

1. (a) Dhingra S.; Kanatzidis M. G. Science 1993, 258, 1769-1772.
2. (b) Chung, D.-Y.; Hogan, T.; Brazis, P.; Rocci-Lane, M.; Kannewurf, C.; Bastea, M.; Uher, C.; Kanatzidis, M. G. Science 2000, 287, 1024-1027.
3. (c) Kanatzidis, M. G.; Sutorik A. Progr. Inorg. Chem. 1995, 43, 151-265.
4. (a) Kumta, P. N.; Risbud, S. H. J. Mater. Sci. 1994, 29, 1135-1158.
5. (b) Volodina, A. N.; Koubchinova, T. B.; Maximova, S. I. Zh. Neorg. Khim. SSSR 1987, 32, 2899-2901.
6. (c) Rolland, B.; McMillan, P.; Molinié, P.; Colombet, P. Eur. J. Solid State Inorg. Chem. 1990, 27, 715-724.
7. (a) Aitken, J. A.; Chondroudis, K.; Young, V. G., Jr.; Kanatzidis, M. G. Inorg. Chem. 2000, 39, 1525-1533.
8. (b) Chondroudis, K.; McCarthy, T. J.; Kanatzidis, M. G. Inorg. Chem. 1996, 35, 840-844.
9. (a) Chondroudis, K.; Kanatzidis, M. G. Inorg. Chem. Commun. 1998, 1/2, 55-57.
10. (b) Chondroudis, K.; Kanatzidis, M. G. Inorg. Chem. 1998, 37, 3792-3797.
11. Carrillo-Cabrera, W.; Peters, K.; von Schnering, H. G.; Menzel, F.; Brockner, W. Z. Anorg. Allg. Chem. 1995, 621, 557561.
12. (a) Chen, J. H.; Dorhout, P. K. Inorg. Chem. 1995, 34, 5705-5706.
13. (b) Chen, J. H.; Dorhout, P. K.; Ostenson, J. E. Inorg. Chem. 1996, 35, 5627-5633.
14. Orgzall, I.; Lorenz, B.; Dorhout, P. K.; Van Calcar, P. M.; Brister, K.; Sander, T.; Hochheimer, H. D. J. Phys. Chem. Solids 2000, 61, 123-134.
15. (a) Evenson, C. R., IV; Dorhout, P. K. Inorg. Chem. 2001, 40, 2884-2891.
16. (b) Evenson, C. R., IV; Dorhout, P. K. Inorg. Chem. 2001, 40, 2875-2883.
17. (a) Gauthier, G.; Jobic, S.; Brec, R.; Rouxel, J. Inorg. Chem. 1998, 37, 2332-2333.
18. (b) Gauthier, G.; Jobic, S.; Danaire, V.; Brec, R.; Evain, M. Acta Crystallogr. 2000, C56, E117.
19. (a) Goh, E.-Y.; Kim, E.-J. Kim, S.-J. J. Solid State Chem. 2001, 160, 195-204.
20. (b) Komm, T.; Schleid, T. Z. Anorg. Allg. Chem. 2004, 630, 712-716.
21. Salvador, J. R.; Guo, F.; Hogan, T.; Kanatzidis, M. G. Nature 2003, 425, 702-705.
22. (a) Cieren, X.; Angenault, J.; Couturier, J.-C.; Jaulmes, S.; Quarton, M.; Robert, F. J. Solid State Chem. 1996, 121, 230-235.
23. (b) Angenault, J.; Cieren, X.; Wallez, G.; Quarton, M. J. Solid State Chem. 2000, 153, 55-65.
24. (c) Evain, M.; Lee, S.; Queignec, M.; Brec, R. J. Solid State Chem. 1987, 71. 139-153.
25. (d) Evain, M.; Queignec, M.; Brec, R.; Rouxel, J. J. Solid State Chem. 1985, 56, 148-157.
26. (e) Evain, M.; Queignec, M.; Brec, R.; Sourisseau, C. J. Solid State Chem. 1988, 75, 413-431.
27. Gieck, C.; Rocker, F.; Ksenofontov, V.; Gütlich, P.; Tremel, W. Angew. Chem., Int. Ed. 2001, 40, 908-911.
28. (a) Chen, B. L.; Eddaoudi, M.; Hyde, S. T.; O'Keeffe, M.; Yaghi, O. M. Science 2001, 291, 1021-1023.
29. (b) Rosi, N. L.; Eddaoudi, M.; Kim, J.; O'Keeffe, M.; Yaghi, O. M. Angew. Chem., Int. Ed. 2001, 41, 284-287.
30. 5 (90%) were isolated by washing away the excess flux with N,N-dimethylformamide. Semiquantitative energy dispersive analysis (EDS) on a number of the orange polyhedra indicated the presence of K, Yb, P, and S in an approximate 6:3:5:20 molar ratio.
31. 2 = 0.1666 for I > 2σ (I). Attempts to find a single crystal were met with great difficulty, so a twinned specimen was selected for data collection. The collected reflections were processed with the program CELLNOW, which found three "twin" components. The second domain was rotated 180° about the 0, 1, -0.5 real axis of the major component. The third domain was rotated 180° about the 0, 1, 0.5 real axis of the major component. The data were integrated on all three components simultaneously using SAINT. TWINABS was used for the absorption correction. The structure was solved with direct methods. The ratio of the three crystal components refined to 78.26:15.19:6.55%.
32. (c) SMART, SAINT, CELLNOW, TWINABS, SHELXTL V-5; Bruker Analytical X-ray Instruments, Inc., Madison, WI, and George Sheldrick.
33. Energy gap was determined from optical diffuse reflectance spectra obtained at room temperature from ground polycrystalline samples over the range of 0.5-6 eV.
34. 5: 594 w, 576 w, 565 w, 536 w, 512 vw, 423 vs, 329 w, 308 w, 265 wb, 202-180 wvb, 161 w (s = strong, w = weak, b = broad, v = very).
35. Wibbelmann, C.; Brockner, W.; Eisenmann, B.; Schäfer, H. Z. Naturforsch 1983, 39a, 190-194.
36. Kittel, C. Introduction to Solid State Physics; John Wiley & Sons: New York, 1996; p 425.
37. Eddaoudi, M.; Kim, J.; Rosi, N.; Vodak, D.; Wächter, J.; O'Keefe, M.; Yaghi, O. M. Science 2002, 295, 469-472.