Flux synthesis of the noncentrosymmetric cluster compounds Cs2SnAs2Q9 (Q = S, Se) containing two different polychalcoarsenite β-[AsQ4]3- and [AsQ5]3- ligands

Inorganic Chemistry

Volumn 42, Issue 5, 2003, Pages 1475-1482

  Iyer, Ratnasabapathy G ^a   Do, Junghwan ^a   Kanatzidis, Mercouri G ^a  

^a MICHIGAN STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ANION; ARSENIC ACID; ARSENIC TRIOXIDE; CESIUM; GLASS; LIGAND; SELENIUM; SULFUR; TIN;

ARTICLE; CHEMICAL STRUCTURE; CRYSTALLIZATION; ENERGY; LIGHT ABSORPTION; SYNTHESIS; THERMAL ANALYSIS;

EID: 0037430179     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic0260771     Document Type: Article

References (35)

1. (a) Vater, V.; Sheldrick, W. S. Z. Naturforsch., B 1998, 53, 1259.
2. (b) Cordier, G.; Schwidetzky, C.; Schäfer, H. Z. Naturforsch., B 1985, 40, 1.
3. (c) Wachhold, M.; Sheldrick, W. S. Z. Naturforsch., B 1997, 52, 169.
4. (d) Wachhold, M.; Sheldrick, W. S. Z. Naturforsch., B 1996, 51, 32.
5. (a) Chou, J.-H.; Hanko, J. A.; Kanatzidis, M. G. Inorg. Chem. 1997, 36, 4.
6. (b) Wachhold, M.; Kanatzidis, M. G. Inorg. Chem. 1999, 38, 4178.
7. (c) Hanko, J. A.; Chou, J.-H.; Kanatzidis, M. G. Inorg. Chem. 1998, 37, 1670.
8. (d) Chou, J.-H.; Kanatzidis, M. G. Inorg. Chem. 1994, 33, 1001.
9. (e) Chou, J.-H.; Kanatzidis, M. G. Inorg. Chem. 1994, 33, 5372.
10. (f) Wachhold, M.; Kanatzidis, M. G. Inorg. Chem. 2000, 39, 2337.
11. (g) Chou, J.-H.; Kanatzidis, M. G. J. Solid State Chem. 1996, 123, 115.
12. (h) Kanatzidis, M. G.; Chou, J.-H. J. Solid State Chem. 1996, 127, 186.
13. (a) Jerome, J. E.; Wood, P. T.; Pennington, W. T.; Kolis, J. W. Inorg. Chem. 1994, 33, 1733.
14. (b) O'Neal, S. C.; Pennington, W. T.; Kolis, J. W. J. Am. Chem. Soc. 1991, 113, 710.
15. (c) O'Neal, S. C.; Pennington, W. T.; Kolis, J. W. Inorg. Chem. 1992, 31, 888.
16. Pertlik F. J. Solid State Chem. 1994, 112, 170.
17. Iyer, R. G.; Kanatzidis, M. G. Inorg. Chem. 2002, 41, 3605.
18. (a) McCarthy, T. J.; Hogan, T.; Kannewurf, C. R.; Kanatzidis, M. G. Chem. Mater. 1994, 6, 1072.
19. (b) Hanko, J. A.; Sayettat, J.; Jobic, S.; Brec, R.; Kanatzidis, M. G. Chem. Mater. 1998, 10, 3040.
20. (a) Chondroudis, K.; McCarthy, T. J.; Kanatzidis, M. G. Inorg. Chem. 1996, 35, 840.
21. (b) Evenson, C. R.; Dorhout, P. K. Inorg. Chem. 2001, 40, 2884.
22. (a) Aitken, J. A.; Canlas, C.; Weliky, D. P.; Kanatzidis, M. G. Inorg. Chem. 2001, 40, 6496.
23. 1/c; a = 17.669 Å, b = 7.1936 Å, c = 24.171 Å, β = 94.256°; R1 = 4.93%, wR2 = 9.19%.
24. SAINT, version 4.05; Siemens Analytical X-ray Instruments: Madison, WI, 1995.
25. 3).
26. (a) Yamada, N.; Ohno, E.; Nishiuchi, K.; Akahira, N.; Takao, M. J. Appl. Phys. 1991, 69 (5), 2849-2856.
27. (b) Rubin, K. A.; Birnie, D. P.; Chen, M. J. Appl. Phys. 1992, 71 (8), 3680-3687.
28. (c) Ohta, T. J. Optoelec. Adv. Mater. 2001, 3 (3), 609-626.
29. (d) Yamada, N.; Matsunaga, T. J. Appl. Phys. 2000, 88 (12), 7020-7028.
30. Definitions: HOMO, highest occupied molecular orbital; LUMO, lowest unoccupied molecular orbital.
31. (a) Dhingra, S.; Kanatzidis, M. G. Science 1992, 258, 1769.
32. (b) Marking, G. A.; Hanko, J. A.; Kanatzidis, M. G. Chem. Mater. 1998, 10, 1191.
33. (a) Bastow, T. J.; Whitfield, H. J. J. Chem. Soc., Dalton Trans. 1973, 1739.
34. (b) Billes, F.; Mitsa, V.; Mateleshko, N.; Fejsa, I. J. Mol. Struct. 1999, 513, 109.
35. (c) Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 5th ed.; John Wiley and Sons: New York, 1997.