메뉴 건너뛰기




Volumn , Issue 29, 2007, Pages 4669-4678

Evidence for ligand-centered reactivity of a 17e radical cationic 2H-azaphosphirene complex

Author keywords

Electron transfer; Ligand centered reactivity; Phosphorus heterocycles

Indexed keywords

CYANIDES; FREE RADICAL REACTIONS; LIGANDS; PHOSPHORUS;

EID: 35348944782     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200700658     Document Type: Article
Times cited : (14)

References (50)
  • 9
    • 0002619581 scopus 로고    scopus 로고
    • and references cited therein. For example, see
    • For example, see: U. Jahn, P. Hartmann, Chem. Commun. 1998, 209-210, and references cited therein.
    • (1998) Chem. Commun , pp. 209-210
    • Jahn, U.1    Hartmann, P.2
  • 27
    • 85163246258 scopus 로고    scopus 로고
    • The numbering of atoms in heterocyclic complexes 3a-h according to the Hantzsch-Widmann-Patterson nomenclature is used in this paper
    • The numbering of atoms in heterocyclic complexes 3a-h according to the Hantzsch-Widmann-Patterson nomenclature is used in this paper.
  • 28
    • 0003516749 scopus 로고
    • 5th ed, Oxford University Press, Oxford
    • P. W. Atkins, Physical Chemistry, 5th ed., Oxford University Press, Oxford, 1994.
    • (1994) Physical Chemistry
    • Atkins, P.W.1
  • 29
    • 85163248311 scopus 로고    scopus 로고
    • Cyclovoltammetric measurements did not reveal conclusive results
    • Cyclovoltammetric measurements did not reveal conclusive results.
  • 31
    • 85163244947 scopus 로고    scopus 로고
    • The ease of electrophilic aromatic substitution increases in the order: thiophene < furane < pyrrol. For example, see: D. T. Davies, Aromatic Heterocyclic Chemistry, Oxford University Press, Oxford, 1992.
    • The ease of electrophilic aromatic substitution increases in the order: thiophene < furane < pyrrol. For example, see: D. T. Davies, Aromatic Heterocyclic Chemistry, Oxford University Press, Oxford, 1992.
  • 32
    • 85163243139 scopus 로고    scopus 로고
    • X-ray crystallographic analysis of 3d: Suitable yellow single crystals of 3d were obtained from a concentrated n-pentane solution upon decreasing the temperature from ambient temperature to +4°C. Data were collected with a Nonius KappaCCD diffractometer equipped with a low-temperature device (Cryostream, Oxford Cryosystems) at 123 K by using graphite monochromated Mo-Kα radiation (λ, 0.71073 Å, The structure was solved by Patterson methods (SHELXS-97, 20a] and refined by full-matrix least-squares on F 2 (SHELXL-97, 20b] All non-hydrogen atoms were refined anisotropically. The hydrogen atoms were included isotropically by using the riding model on the bound atoms. The thiophene substituent is disordered [occupancy: 0.81(1, 0.19(1, Semiempirical absorption correction was carried out from equivalents min./max. transmissions, 0.27295/0.61685, C 24H27N2
    • -3. CCDC-646819 (for 3b), -639472 (for 3d), and -646820 (for 3e) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
  • 33
    • 85163249676 scopus 로고    scopus 로고
    • SHELXS-97: G. M. Sheldrick, Acta Crystallogr., Sect. A 1990, 46, 467-473;
    • a) SHELXS-97: G. M. Sheldrick, Acta Crystallogr., Sect. A 1990, 46, 467-473;
  • 34
    • 85163246667 scopus 로고    scopus 로고
    • G. M. Sheldrick, SHELXL-97, University of Göttingen, 1997.
    • b) G. M. Sheldrick, SHELXL-97, University of Göttingen, 1997.
  • 37
    • 85163245981 scopus 로고    scopus 로고
    • 2NCN (2a), but also for the reactions with the electron-rich five-membered heterocyclic nitrile derivatives 2b-e.
    • 2NCN (2a), but also for the reactions with the electron-rich five-membered heterocyclic nitrile derivatives 2b-e.
  • 38
    • 85163242472 scopus 로고    scopus 로고
    • TURBOMOLE V5.8: see http://www.cosmologic.de/Quantum-Chemistry/ main_turbomole.html.
    • TURBOMOLE V5.8: See


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.