Synthesis of functional Δ3-1,3,5-oxazaphospholene and 2H-1,4,2-diazaphosphole complexes via catalytic ring expansion reactions of a 2H-azaphosphirene complex

Tetrahedron

Volumn 59, Issue 33, 2003, Pages 6213-6220

  Neumann, Christoph ^a   Junquera, Andrea Prehn ^a   Wismach, Cathleen ^a   Jones, Peter G ^a   Streubel, Rainer ^b  

^a TECHNICAL UNIVERSITY OF BRAUNSCHWEIG   (Germany)

^b UNIVERSITY OF BONN   (Germany)

Author keywords

2H 1,4,2 diazaphosphole; 2H azaphosphirene; Catalytic ring expansion; Tungsten; 3 1,3,5 oxazaphospholene

Indexed keywords

4 HYDROXYBENZALDEHYDE; ACETONE; ALKENE DERIVATIVE; BENZALDEHYDE; BENZONITRILE; CARBONYL DERIVATIVE; CYCLOHEXANONE; DELTA3 1,3,5 OXAZAPHOSPHOLENE; KETONE DERIVATIVE; PENTACARBONYL[2 BIS(TRIMETHYLSILYL)METHYL 3 PHENYL 1,4,2 OXAZAPHOPHASPIRO[4.5]DEC 3 ENE KAPPAP]TUNGSTEN; PENTACARBONYL[2 BIS(TRIMETHYLSILYL)METHYL 5 (2 AMINOPHENYL) 3 PHENYL 2H 1,4,2 DIAZAPHOSPHOLE KAPPAP]TUNGSTEN; PENTACARBONYL[2 BIS(TRIMETHYLSILYL)METHYL 5 (2 HYDROXYPHENYL) 3 PHENYL 2H 1,4,2 DIAZAPHOSPHOLE KAPPAP]TUNGSTEN; PENTACARBONYL[2 BIS(TRIMETHYLSILYL)METHYL 5 (4 AMINOPHENYL) 3 PHENYL 2H 1,4,2 DIAZAPHOSPHOLE KAPPAP]TUNGSTEN; PENTACARBONYL[2 BIS(TRIMETHYLSILYL)METHYL 5 (4 HYDROXYPHENYL) 3 PHENYL 2H 1,4,2 DIAZAPHOSPHOLE KAPPAP]TUNGSTEN; PENTACARBONYL[5 BIS(TRIMETHYLSILYL)METHYL 2 (4 HYDROXYPHENYL) 4 PHENYL DELTA3 1,3,5 OXAZAPHOSPHOLENE KAPPAP]TUNGSTEN; PENTACARBONYL[5 BIS(TRIMETHYLSILYL)METHYL 2,2 DIMETHYL 4 PHENYL DELTA3 1,3,5 OXAZAPHOSPHOLENE KAPPAP]TUNGSTEN; PENTACARBONYL[5 BIS(TRIMETHYLSILYL)METHYL 2,4 DIPHENYL DELTA3 1,3,5 OXAZAPHOSPHOLENE KAPPAP]TUNGSTEN; PHOSPHOLE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CATALYSIS; CATALYST; CRYSTAL STRUCTURE; INFRARED SPECTROSCOPY; MASS SPECTROMETRY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PRIORITY JOURNAL; PROTON NUCLEAR MAGNETIC RESONANCE; SYNTHESIS; X RAY ANALYSIS; X RAY DIFFRACTION;

EID: 0043206055     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(03)01044-5     Document Type: Article

References (10)

1. Streubel R. Coord. Chem. Rev. 227:2002;172.
2. Streubel R. Top. Curr. Chem. 223:2002;91.
3. Wilkens H., Ruthe F., Jones P.G., Streubel R. Chem. Eur. J. 4:1998;1542.
4. Streubel R., Wilkens H., Jones P.G. Chem. Eur. J. 21:2000;3997.
5. Streubel R., Neumann C., Jones P.G. J. Chem. Soc., Dalton Trans. 2000;2495.
6. Neumann C., Ionescu E., Schiemann U., Schlenker M., Bode M., Ruthe F., Jones P.G., Streubel R. J. Organomet. Chem. 643-644:2002;1226.
7. Streubel R., Ostrowski A., Priemer S., Rohde U., Jeske J., Jones P.G. Eur. J. Inorg. Chem. 1998;257.
8. Wilkens, H. Ph.D. Thesis, Braunschweig, 2000.
9. Sheldrick, G.M. SHELXL-97: Program for crystal structure refinement; Univesität Göttingen, 1997.
10. Crystallographic data (excluding structure factors) for the structure reported in this paper has been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC 212332 and 21333. Copies of the data can be obtained free of charge on application to The Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK [fax: int. code +44-1223-336-033].