Imidoyl radicals in organic synthesis

Current Organic Chemistry

Volumn 11, Issue 15, 2007, Pages 1366-1384

  Minozzi, Matteo ^a   Nanni, Daniele ^a   Spagnolo, Piero ^a  

^a UNIVERSITY OF BOLOGNA   (Italy)

Author keywords

Azo bis iso butyronitrile; Benzophenone; Di tert butyl peroxide; Electron withdrawing groups; Isothiocyanates

Indexed keywords

ATOMS; CARBON; CYCLIZATION; REACTION INTERMEDIATES;

ALDIMINES; AZO-BIS-ISO-BUTYRONITRILE; BENZOPHENONE; DI-TERT BUTYL PEROXIDE; ELECTRON WITHDRAWING GROUP; HETEROATOMS; HYDROGEN ATOM ABSTRACTION; ISONITRILES; ISOTHIOCYANATES; ORGANIC SYNTHESIS;

CARBONYL COMPOUNDS;

ANTINEOPLASTIC AGENT; AROMATIC COMPOUND; BENZOPHENONE; BENZOTHIAZOLE DERIVATIVE; BENZOTHIENOQUINOLINE DERIVATIVE; BENZOTHIENOQUINOXALINE; CAMPTOTHECIN; CARBAMAZEPINE; DIBENZAZEPINE; DIBENZOXAZEPINE DERIVATIVE; ELLIPTICINE; IMINE; IRINOTECAN; ISONITRILE DERIVATIVE; ISOTHIOCYANIC ACID DERIVATIVE; MAPPICINE; ORGANIC COMPOUND; OXCARBAZEPINE; PHENYTOIN; QUINOLINE DERIVATIVE; QUINOLONE DERIVATIVE; QUINOXALINE DERIVATIVE; SILATECAN; SPIROCYCLOHEXADIENYL DERIVATIVE; TELLUROIMIDATE DERIVATIVE; TOPOTECAN; UNCLASSIFIED DRUG;

ANNULATION REACTION; ANTICONVULSANT ACTIVITY; CANCER CHEMOTHERAPY; CHEMICAL ANALYSIS; CHEMICAL BOND; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; CONFORMATIONAL TRANSITION; CYCLIZATION; DRUG STRUCTURE; DRUG SYNTHESIS; ENANTIOSELECTIVITY; ISOMERIZATION; NUCLEAR OVERHAUSER EFFECT; ORGANIC CHEMISTRY; REVIEW; SOLID TUMOR; SPECTROSCOPY; STEREOCHEMISTRY; SUBSTITUTION REACTION; SYNTHESIS;

EID: 35348914314     PISSN: 13852728     EISSN: None     Source Type: Journal    
DOI: 10.2174/138527207782023120     Document Type: Review

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135. In these reactions even α-fragmentation with loss of a sulfanyl radical does not seem a drawback, since isonitriles and disulfides were only detected in few cases and just in trace amounts.