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note
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9Te: C, 52.90; H, 5.18; N, 2.06. Found: C, 52.64; H, 5.14; N, 2.02.
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18
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0003921987
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Viehe, H. G.; Janousek, Z.; Merényi, R., Eds; D Reidel Publishing Company: Dordecht
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10. The formation of the α-isomer can be explained by considering the anomeric effect of the glycos-1-yl radicals. However, the origin of the β-selectivity is not clear at the present time. One possible explanation may be an involvement of an intramolecualr participation of the polar C-2 phthaloyl group to the glycos-1-yl radical to shield the α-face, because such acyloxy group participation and rearrangement have already been reported. See, Giese, B.; Dupuis, J.; Gröninger, K.; Hasskerl, T.; Nix, M.; Weizel, T. Substituent Effects in Radical Chemistry; Viehe, H. G.; Janousek, Z.; Merényi, R., Eds; D Reidel Publishing Company: Dordecht, 1986; p283.
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