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It should be noted that there are contradicting results in the literature as to the quality of monolayers made by μCP. For example, Eberhardt et. al, Eberhardt, A. S, Nyquist, R. M, Parikh, A. N, Zawodzinski, T, Swanson, B. I. Langmuir 1999, 15, 1595-1598, have reported that printed monolayers had much better translational order and higher packing density than those formed by solution
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Larsen et al. (Larsen, N. B.; Biebuyck, H.; Delamarche, E.; Michel, B. J. Am. Chem. Soc. 1997, 119, 3017-3026) have shown monolayers formed from μCP have characteristics indistinguishable from monolayers formed from solution. These different findings may be attributed to the many factors that may affect the number of defects such as the stamp dimensions, the method of inking and stamping, and the roughness of the substrate to name a few, which make it challenging to quantify defects.
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