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Volumn , Issue 18, 2007, Pages 2867-2871

Reluctant cross-metathesis reactions: The highly beneficial effect of microwave irradiation

Author keywords

Carbene complexes; Catalysis; Cross coupling; Metathesis; Olefination

Indexed keywords

CATALYSIS; COMPLEXATION; IRRADIATION; MICROWAVES; REACTION KINETICS;

EID: 34948822775     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2007-983825     Document Type: Article
Times cited : (32)

References (36)
  • 14
    • 0001193782 scopus 로고
    • For CM of acrylonitrile with a molybdenum-based catalyst, see: i
    • For CM of acrylonitrile with a molybdenum-based catalyst, see: (i) Crowe, W. E.; Goldberg, D. R. J. Am. Chem. Soc. 1995, 117, 5162.
    • (1995) J. Am. Chem. Soc , vol.117 , pp. 5162
    • Crowe, W.E.1    Goldberg, D.R.2
  • 15
    • 11144325118 scopus 로고    scopus 로고
    • For reviews on microwave-assisted synthesis, see: a
    • For reviews on microwave-assisted synthesis, see: (a) Kappe, C. O. Angew. Chem. Int. Ed. 2004, 43, 6250.
    • (2004) Angew. Chem. Int. Ed , vol.43 , pp. 6250
    • Kappe, C.O.1
  • 36
    • 24644491818 scopus 로고    scopus 로고
    • As CM is a reversible process, the TON (turnover number) represents the average number of substrate molecules converted into the cross product per molecule of catalyst. A typical loading of 1a,b in CM reaction is 2-10%, which corresponds to a maximum TON of 10-50. For a recent TON study in ruthenium carbene catalyzed ring-closing metathesis, see: Maechling, S.; Zaja, M.; Blechert, S. Adv. Synth. Catal. 2005, 347, 1413.
    • As CM is a reversible process, the TON (turnover number) represents the average number of substrate molecules converted into the cross product per molecule of catalyst. A typical loading of 1a,b in CM reaction is 2-10%, which corresponds to a maximum TON of 10-50. For a recent TON study in ruthenium carbene catalyzed ring-closing metathesis, see: Maechling, S.; Zaja, M.; Blechert, S. Adv. Synth. Catal. 2005, 347, 1413.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.