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6-Bromo-2,3-(methylenedioxy)benzoic acid was prepared by the carboxylation of 3,4-(methylenedioxy)phenylbromide (72% yield) according to: a) P. A. Plé, T. P. Green, L. F. Hennequin, J. Curwen, M. Fennell, J. Allen, C. L. Brempt, G. Costello, J. Med. Chem. 2004, 47, 871-887,
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and also by the bromination of 2,3-(methylenedioxy)benzoic acid with DBDMH (62% yield, by a modification of the method reported for a dimethoxy derivative) according to: b) J. Auerbach, S. A. Weissman, T. J. Blacklock, M. R. Angeles, K. Hoogsteen, Tetrahedron Lett. 1993, 34, 931-934;
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and also by the bromination of 2,3-(methylenedioxy)benzoic acid with DBDMH (62% yield, by a modification of the method reported for a dimethoxy derivative) according to: b) J. Auerbach, S. A. Weissman, T. J. Blacklock, M. R. Angeles, K. Hoogsteen, Tetrahedron Lett. 1993, 34, 931-934;
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