-
1
-
-
33947139526
-
-
a) L. Friebe, O. Nuyken, W. Obrecht, Adv. Polym. Sci. 2006, 204, 1;
-
(2006)
Adv. Polym. Sci
, vol.204
, pp. 1
-
-
Friebe, L.1
Nuyken, O.2
Obrecht, W.3
-
3
-
-
0038401605
-
-
Eds, K. A. Gschneider, Jr, L. Fleming, Elsevier Science Publishers, Dordrecht, chapter 61;
-
a) Z. Shen, J. Ouyang in Handbook on the Physics and Chemistry of Rare Earth (Eds.: K. A. Gschneider, Jr., L. Fleming), Elsevier Science Publishers, Dordrecht, 1987, chapter 61;
-
(1987)
Handbook on the Physics and Chemistry of Rare Earth
-
-
Shen, Z.1
Ouyang, J.2
-
4
-
-
0003616618
-
-
Eds, B. Cornils, W. A. Herrmann, Wiley-VCH, Weinheim
-
b) R. Taube, G. Sylvester in Applied Homogenous Catalysis with Organometallic Compounds (Eds.: B. Cornils, W. A. Herrmann), Wiley-VCH, Weinheim, 2002, p. 280.
-
(2002)
Applied Homogenous Catalysis with Organometallic Compounds
, pp. 280
-
-
Taube, R.1
Sylvester, G.2
-
5
-
-
33645832965
-
-
A. Fischbach, F. Perdih, E. Herdtweck, R. Anwander, Organometallics 2006, 25, 1626.
-
(2006)
Organometallics
, vol.25
, pp. 1626
-
-
Fischbach, A.1
Perdih, F.2
Herdtweck, E.3
Anwander, R.4
-
6
-
-
33750323581
-
-
A. Fischbach, C. Meermann, G. Eickerling, W. Scherer, R. Anwander, Macromolecules 2006, 39, 6811.
-
(2006)
Macromolecules
, vol.39
, pp. 6811
-
-
Fischbach, A.1
Meermann, C.2
Eickerling, G.3
Scherer, W.4
Anwander, R.5
-
7
-
-
12444270376
-
-
A. Fischbach, M. G. Klimpel, M. Widenmeyer, E. Herdtweck, W. Scherer, R. Anwander, Angew. Chem. 2004, 116, 2284;
-
(2004)
Angew. Chem
, vol.116
, pp. 2284
-
-
Fischbach, A.1
Klimpel, M.G.2
Widenmeyer, M.3
Herdtweck, E.4
Scherer, W.5
Anwander, R.6
-
8
-
-
4544351220
-
-
Angew. Chem. Int. Ed. 2004, 43, 2234.
-
(2004)
Chem. Int. Ed
, vol.43
, pp. 2234
-
-
Angew1
-
9
-
-
0000528811
-
-
X-ray crystallographically characterized rare-earth-metal mixed halide/alkyl complexes feature bulky alkyl and aryl ligands; for examples, see: a C. Eaborn, P. B. Hitchcock, K. Izod, J. D. Smith, J. Am. Chem. Soc. 1994, 116, 12 071;
-
X-ray crystallographically characterized rare-earth-metal mixed halide/alkyl complexes feature bulky alkyl and aryl ligands; for examples, see: a) C. Eaborn, P. B. Hitchcock, K. Izod, J. D. Smith, J. Am. Chem. Soc. 1994, 116, 12 071;
-
-
-
-
10
-
-
0000607015
-
-
b) C. Eaborn, P. B. Hitchcock, K. Izod, Z.-R. Lu, J. D. Smith, Organometallics 1996, 15, 4783;
-
(1996)
Organometallics
, vol.15
, pp. 4783
-
-
Eaborn, C.1
Hitchcock, P.B.2
Izod, K.3
Lu, Z.-R.4
Smith, J.D.5
-
11
-
-
0035805674
-
-
2682, and references therein;
-
c) G. W. Rabe, C. D. Bérubé, G. P. A. Yap, Inorg. Chem. 2001, 40, 2682, and references therein;
-
(2001)
Inorg. Chem
, vol.40
-
-
Rabe, G.W.1
Bérubé, C.D.2
Yap, G.P.A.3
-
13
-
-
0000078595
-
-
a) S. Maiwald, H. Weißenborn, H. Windisch, C. Sommer, G. Müller, R. Taube, Macromol. Chem. Phys. 1997, 198, 3305;
-
(1997)
Macromol. Chem. Phys
, vol.198
, pp. 3305
-
-
Maiwald, S.1
Weißenborn, H.2
Windisch, H.3
Sommer, C.4
Müller, G.5
Taube, R.6
-
14
-
-
0000132327
-
-
b) S. Maiwald, R. Taube, H. Hemling, H. Schumann, J. Organomet. Chem. 1998, 552, 195;
-
(1998)
J. Organomet. Chem
, vol.552
, pp. 195
-
-
Maiwald, S.1
Taube, R.2
Hemling, H.3
Schumann, H.4
-
15
-
-
0035877940
-
-
c) S. Maiwald, C. Sommer, G. Müller, R. Taube, Macromol. Chem. Phys. 2001, 202, 1446.
-
(2001)
Macromol. Chem. Phys
, vol.202
, pp. 1446
-
-
Maiwald, S.1
Sommer, C.2
Müller, G.3
Taube, R.4
-
16
-
-
33745710717
-
-
S. Arndt, K. Beckerle, P. M. Zeimentz, T. Spaniol, J. Okuda, Angew. Chem. 2005, 117, 7640;
-
(2005)
Angew. Chem
, vol.117
, pp. 7640
-
-
Arndt, S.1
Beckerle, K.2
Zeimentz, P.M.3
Spaniol, T.4
Okuda, J.5
-
17
-
-
28044443397
-
-
Angew. Chem. Int. Ed. 2005, 44, 7473.
-
(2005)
Chem. Int. Ed
, vol.44
, pp. 7473
-
-
Angew1
-
18
-
-
33749115448
-
-
R. Anwander, O. Runte, J. Eppinger, G. Gerstberger, E. Herdtweck, M. Spiegler, J. Chem. Soc. Dalton Trans. 1998, 847.
-
(1998)
J. Chem. Soc. Dalton Trans
, pp. 847
-
-
Anwander, R.1
Runte, O.2
Eppinger, J.3
Gerstberger, G.4
Herdtweck, E.5
Spiegler, M.6
-
19
-
-
37049088544
-
-
H. C. Aspinall, D. C. Bradley, M. B. Hursthouse, K. D. Sales, N. P. C. Walker, B. Hussain, J. Chem. Soc. Dalton Trans. 1989, 623.
-
(1989)
J. Chem. Soc. Dalton Trans
, pp. 623
-
-
Aspinall, H.C.1
Bradley, D.C.2
Hursthouse, M.B.3
Sales, K.D.4
Walker, N.P.C.5
Hussain, B.6
-
22
-
-
0033447443
-
-
M. Karl, G. Seybert, W. Massa, K. Dehnicke, Z. Anorg. Allg. Chem. 1999, 625, 375.
-
(1999)
Z. Anorg. Allg. Chem
, vol.625
, pp. 375
-
-
Karl, M.1
Seybert, G.2
Massa, W.3
Dehnicke, K.4
-
23
-
-
34548314892
-
-
Compound 2b (C24H72Cl2N 4O2Si8Y2, Mr, 922.30) crystallizes from hexane in the triclinic space group P1 with a, 13.1068(4, b, 13.4850(4, c, 16.1737(5) Å, α, 96.766(1, β, 101.307(1, γ, 116.598(1)°, V, 2436.60(13) Å3, dcalcd, 1.257 g cm -3 for Z, 2. Data were collected at 123 K on a BRUKER-AXS 2K CCD system. The structure was solved by direct methods and least-square refinement of the model converged to a final R1, 0.0248 (9778 reflections, I > 2.0σ(I, and wR2, 0.0604 (all data, 11 638 reflections, Compound 4a (C28H 86Cl4N5Nd3O2Si 10, Mr, 1380.44) crystallizes from hexane in the monoclinic space group P21/c wi
-
-3 for Z = 4. Data were collected at 123 K on a BRUKER-AXS 2K CCD system. The structure was solved by direct methods and least-square refinement of the model converged to a final R1 = 0.0302 (11 154 reflections, I > 2.0σ(I)) and wR2 = 0.0550 (all data, 14 571 reflections). CCDC-628824 to CCDC-628826) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
-
-
-
-
24
-
-
34548325112
-
-
2-mediated tetrahydrofuran solvent degradation.
-
2-mediated tetrahydrofuran solvent degradation.
-
-
-
-
25
-
-
84944508767
-
-
W. A. Herrmann, R. Anwander, F. C. Munck, W. Scherer, V. Dufaud, N. W. Huber, G. R. J. Artus, Z. Naturforsch. B 1994, 49, 1789.
-
(1994)
Z. Naturforsch. B
, vol.49
, pp. 1789
-
-
Herrmann, W.A.1
Anwander, R.2
Munck, F.C.3
Scherer, W.4
Dufaud, V.5
Huber, N.W.6
Artus, G.R.J.7
-
26
-
-
34548305549
-
-
H. M. Dietrich, O. Schuster, K. W. Törnroos, R. Anwander, Angew. Chem. 2006, 118, 4977;
-
(2006)
Angew. Chem
, vol.118
, pp. 4977
-
-
Dietrich, H.M.1
Schuster, O.2
Törnroos, K.W.3
Anwander, R.4
-
27
-
-
33746903178
-
-
Angew. Chem. Int. Ed. 2006, 45, 4858.
-
(2006)
Chem. Int. Ed
, vol.45
, pp. 4858
-
-
Angew1
-
28
-
-
34548325111
-
-
Although Ln-NR2→Ln-alkyl transformation is the predominant reaction pathway, significant ligand redistribution reactions and occlusion of nitrogen- and aluminum-containing coproducts is suggested by the microanalytical data. These contaminations N 0.6-1.2, Al 2.1-6.9, which depend on the reaction scale, rule out the formation of pure [Me 2YCl]n or [Me5Nd3Cl 4]n under these reaction conditions
-
n under these reaction conditions.
-
-
-
-
29
-
-
33845435224
-
-
H. M. Dietrich, G. Raudaschl-Sieber, R. Anwander, Angew. Chem. 2005, 117, 5437;
-
(2005)
Angew. Chem
, vol.117
, pp. 5437
-
-
Dietrich, H.M.1
Raudaschl-Sieber, G.2
Anwander, R.3
-
30
-
-
24044545871
-
-
Angew. Chem. Int. Ed. 2005, 44, 5303.
-
(2005)
Chem. Int. Ed
, vol.44
, pp. 5303
-
-
Angew1
-
31
-
-
0003359919
-
-
R. Anwander, C. Palm, O. Groeger, G. Engelhardt, Organometallics 1998, 17, 2027.
-
(1998)
Organometallics
, vol.17
, pp. 2027
-
-
Anwander, R.1
Palm, C.2
Groeger, O.3
Engelhardt, G.4
-
32
-
-
1842818029
-
-
S. Arndt, T. P. Spaniol, J. Okuda, Angew. Chem. 2003, 115, 5229;
-
(2003)
Angew. Chem
, vol.115
, pp. 5229
-
-
Arndt, S.1
Spaniol, T.P.2
Okuda, J.3
-
33
-
-
0242323505
-
-
Angew. Chem. Int. Ed. 2003, 42, 5075.
-
(2003)
Chem. Int. Ed
, vol.42
, pp. 5075
-
-
Angew1
-
34
-
-
33751158398
-
-
P. Sobota, J. Utko, S. Szafert, Inorg. Chem. 1994, 33, 5203.
-
(1994)
Inorg. Chem
, vol.33
, pp. 5203
-
-
Sobota, P.1
Utko, J.2
Szafert, S.3
-
35
-
-
33748556850
-
-
H. M. Dietrich, C. Meermann, K. W. Törnroos, R. Anwander, Organometallics 2006, 25, 4316.
-
(2006)
Organometallics
, vol.25
, pp. 4316
-
-
Dietrich, H.M.1
Meermann, C.2
Törnroos, K.W.3
Anwander, R.4
-
36
-
-
0037076577
-
-
S. Maiwald, C. Sommer, G. Müller, R. Taube, Macromol. Chem. Phys. 2002, 203, 1029.
-
(2002)
Macromol. Chem. Phys
, vol.203
, pp. 1029
-
-
Maiwald, S.1
Sommer, C.2
Müller, G.3
Taube, R.4
-
37
-
-
18844374180
-
-
3-mediated Ln-butenyl(allyl)→Ln-Me(aluminate) transformation might occur under these reaction conditions: W. J. Evans, S. A. Kozimor, J. C. Brady, B. L. Davis, G. W. Nyce, C. A. Seibel, J. W. Ziller, R. J. Doedens, Organometallics 2005, 24, 2269.
-
3-mediated Ln-butenyl(allyl)→Ln-Me(aluminate) transformation might occur under these reaction conditions: W. J. Evans, S. A. Kozimor, J. C. Brady, B. L. Davis, G. W. Nyce, C. A. Seibel, J. W. Ziller, R. J. Doedens, Organometallics 2005, 24, 2269.
-
-
-
-
38
-
-
0037958755
-
-
P. G. Hayes, W. E. Piers, M. Parvez, J. Am. Chem. Soc. 2003, 125, 5622.
-
(2003)
J. Am. Chem. Soc
, vol.125
, pp. 5622
-
-
Hayes, P.G.1
Piers, W.E.2
Parvez, M.3
-
39
-
-
34548323058
-
-
We were not able to control the chlorination of [Nd(AlMe 4)3] to generate pure [Me2NdCl] n. Separation of AlMe3 during the chlorination was unequivocally proven by 13C and 27Al NMR spectroscopic examination of the reaction of [Y(AlMe4)3] with Ph 3CCl; [Nd(AlMe4)3]/Ph3CCl (1:1) in hexane gave a solid 5d″ which polymerizes isoprene comparably to 5d and 5d′
-
3CCl (1:1) in hexane gave a solid 5d″ which polymerizes isoprene comparably to 5d and 5d′.
-
-
-
-
40
-
-
34548298247
-
-
Similar molecular weight distributions have been reported for the binary systems [Nd(OC6H3iPr-2,6)3(AlMe 3)2]/Et2AlCl (Mn/ Mw, 2.03)[4] and [Nd(neopentanolate) 3(AlMe3)3]/Et2AlCl (M n/Mw, 1.74)[4] as well as [Nd(AlMe 4)3]/Et2AlCl immobilized on MCM-48 Mn/Mw, 1.33-1.88, 5
-
[5]
-
-
-
-
41
-
-
34548300338
-
-
4] was previously described to not catalyze the polymerization of isoprene; Ref. [8].
-
4] was previously described to not catalyze the polymerization of isoprene; Ref. [8].
-
-
-
-
42
-
-
2142826739
-
-
V. Monteil, R. Spitz, C. Boisson, Polym. Int. 2004, 53, 576.
-
(2004)
Polym. Int
, vol.53
, pp. 576
-
-
Monteil, V.1
Spitz, R.2
Boisson, C.3
|