Resolution of bridging oxygen signals from O 1s spectra of silicate glasses using XPS: Implications for O and Si speciation

Geochimica et Cosmochimica Acta

Volumn 71, Issue 17, 2007, Pages 4297-4313

  Dalby, Kim N ^a   Nesbitt, H Wayne ^a   Zakaznova Herzog, Valentina P ^b   King, Penelope L ^a  

^a UNIVERSITY OF WESTERN ONTARIO   (Canada)

^b ETH ZURICH   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

EQUILIBRIUM; EXPERIMENTAL MINERALOGY; GLASS; OXYGEN; SILICATE; SPECIATION (CHEMISTRY); THERMODYNAMICS; X-RAY SPECTROSCOPY;

EID: 34548174993     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.gca.2007.07.005     Document Type: Article

References (46)

1. Abou-El-Azm A., and Hussein A. Infra-red transmission of glasses containing high proportions of lead oxide in relation to their structure. Glastechnische Berichte-Glass Science and Technology VI (1959) 66-83
2. Akutagawa J., Yamamoto D., and Pong W. Soft X-ray induced darkening of glass surfaces. Journal of Electron Spectroscopy and Related Phenomena 82 (1996) 75-77
3. Allwardt J.R., Lee S.K., and Stebbins J.F. Bonding preferences of non-bridging O atoms: evidence from 17O MAS and 3QMAS NMR on calcium aluminate and low-silica Ca-aluminosilicate glasses. American Mineralogist 88 (2003) 949-954
4. Allwardt J.R., and Stebbins J.F. Ca-Mg and K-Mg mixing around non-bridging O atoms in silicate glasses: an investigation using 17O MAS and 3QMAS NMR. American Mineralogist 89 (2004) 777-784
5. Calas G., Henderson G.S., and Stebbins J.F. Glasses and melts: linking geochemistry and materials science. Elements 2 5 (2006) 265-268
6. Dalby K.N., and King P.L. A new approach to determine and quantify structural units in silicate glasses using micro-reflectance Fourier-Transform Infrared spectroscopy. American Mineralogist 91 11-12 (2006) 1783-1794
7. Du L.-S., and Stebbins J.F. Network connectivity in aluminoborosilicate glasses: a high resolution 11B, 27Al, and 17O NMR study. Journal of Non-Crystalline Solids 351 (2005) 3508-3520
8. Fayon F., Bessada C., Massiot D., Farnan I., and Coutures J. 29Si and 207Pb NMR study of local order in lead silicate glasses. Journal of Non-Crystalline Glasses (1998) 403-408
9. 2+ environment in lead silicate glasses probed by Pb-LIII edge XAFS and 207Pb NMR. Journal of Non-Crystalline Solids 243 (1999) 39-44
10. Furukawa T., Brawer S., and White W. The structure of lead silicate glasses determined by vibrational spectroscopy. Journal of Materials Science 13 (1978) 268-282
11. Gee I.A., Holland D., and McConville C.F. Atomic environments in binary lead silicate and ternary alkali lead silicate glasses. Physics and Chemistry of Glasses 42 6 (2001) 339-348
12. 2. National Bureau of Standards 13 (1934) 237-244
13. 2. Chemical Geology 213 1-3 (2004) 115-123
14. Henderson G.S. The structure of silicate melts: a glass perspective. The Canadian Mineralogist 43 (2005) 1921-1958
15. 2 melts: structure and thermodynamics of mixing. Geochimica et Cosmochimica Acta 39 (1975) 671-687
16. Hess P. Chapter 5: The nature of silicate melts. In: Hess P. (Ed). Origin of Igneous Rocks (1989), Harvard University Press, Cambridge, MA 59-72 316-329
17. 2. Journal of Non-Crystalline Solids 85 (1986) 393-412
18. Jablonski A., and Powell C.J. Information depth and the mean escape depth in Auger electron spectroscopy and X-ray photoelectron spectroscopy. Journal of Vacuum Science and Technology A21 1 (2003) 274-283
19. Jen J.S., and Kalinowski M.R. An ESCA study of the bridging to non-bridging oxygen ratio in sodium silicate glass and the correlations to glass density and refractive index. Journal of Non-Crystalline Solids 38-39 (1989) 21-26
20. Karlsson C., Zanghellini E., Swenson J., Roling B., Bowron D.T., and Borjesson L. Structure of mixed alkali/alkaline-earth silicate glasses from neutron diffraction and vibrational spectroscopy. Physical Review B 72 (2005) 064206
21. Lee S.K., and Stebbins J.F. The extent of inter-mixing among framework units in silicate glasses and melts. Geochimica et Cosmochimica Acta 66 (2002) 303-309
22. Lee S.K., Cody G.O., and Mysen B. Structure and the extent of disorder in quaternary (Ca-Mg and Ca-Na) aluminosilicate glasses and melts. American Mineralogist 90 (2005) 1393-1401
23. Liu L. Infrared spectroscopy on lead silicate glasses. Condensed Matter B90 (1993) 393-399
24. Maekawa H., Maekawa T., Kawamura K., and Yokokawa T. The structural groups of alkali silicate glasses determined from 29Si MAS-NMR. Journal of Non-Crystalline Solids 127 (1991) 53-64
25. Metson J.B. Charge compensation and binding energy referencing in XPS analysis. Surface and Interface Analysis 27 (1999) 1069-1072
26. 2 glass. Journal of Non-Crystalline Solids 53 (1982) 173-182
27. Mydlar M., Kreidl N., Hendren J., and Clayton G. X-ray diffraction study of lead silicate glasses. Physics and Chemistry of Glasses 11 (1970) 196-204
28. Mysen B., Finger L., Virgo D., and Seifert F. Curve fitting of Raman spectra of silicate glasses. American Mineralogist 67 (1982) 686-695
29. Mysen B., and Richet P. Silicate Glasses and Melts: Properties and Structure (2005), Elsevier, Amsterdam
30. Navrotsky A., Geisinger K.L., McMillan P., and Gibbs G.V. The tetrahedral framework in glasses and melts-inferences from molecular orbital calculations and implications for structure, thermodynamics, and physical properties. Physics and Chemistry of Minerals 11 6 (1985) 284-298
31. Nesbitt H.W., Bancroft G.M., Davidson R., McIntyre N.S., and Pratt A.R. Minimum XPS core-level line widths of insulators, including silicate minerals. American Mineralogist 89 (2004) 878-882
32. 2 melts: interpretation of thermochemical, conductivity, and density data. Geochimica et Cosmochimica Acta 45 (1981) 235-244
33. Piriou B., and Arashi H. Raman and infrared investigations of lead silicate glasses. High Temperature Science 13 (1980) 299-313
34. Richardson F.D., and Webb L.E. Oxygen in molten lead and thermodynamics of lead oxide-silica melts. Bulletin-Institution of Mining and Metallurgy 584 (1955) 529-564
35. Sharma A., Jain H., and Miller A.C. Surface modification of a silicate glass during XPS experiments. Surface and Interface Analysis 31 (2001) 369-374
36. 2, studied by X-ray photoelectron spectroscopy. Journal of Non-Crystalline Solids 48 (1982) 423-430
37. Stebbins, J. (1995) Dynamics and structure of silicate and oxide melts: Nuclear Magnetic Resonance studies. In Mineralogical Society of America Reviews in Mineralogy, Vol. 32 (eds. J. Stebbins, P. McMillan, and D. Dingwell), pp. 191-246.
38. Stebbins J.F. Identification of multiple structural species in silicate glasses by 29Si NMR. Nature 330 (1987) 465-467
39. Sutherland D.G.J., Bancroft G.M., and Tan K.H. Vibrational splitting in Si 2p core-level photoelectron spectra of silicon molecules. Journal of Physical Chemistry 97 11 (1992) 1938-7918
40. Toop G., and Samis C. Activities of ions in silicate melts. Transactions of the Metallurgical Society of the American Institute of Mining, Metallurgical, and Petroleum Engineers 224 (1962) 878-887
41. Wang P., and Zhang L. Structural role of lead in lead silicate glasses derived from XPS spectra. Journal of Non-Crystalline Solids 194 (1996) 129-134
42. Wang P.W., Zhang L.P., Lu L., LeMone D.V., and Kinser D.L. Surface modification of lead silicate glasses under X-ray irradiation. Applied Surface Science 84 (1995) 75-83
43. You J., Jian G., and Xu K. High temperature Raman spectra of sodium disilicate crystal, glass and its liquid. Journal of Non-Crystalline Solids 282 (2001) 125-131
44. Zakaznova-Herzog V.P., Nesbitt H.W., Bancroft G.M., and Tse J.S. High resolution core and valence band XPS spectra of non-conductor pyroxenes. Surface Science 600 (2006) 3175-3186
45. Zakaznova-Herzog V.P., Nesbitt H.W., Bancroft G.M., Tse J.S., Gao X., and Skinner W. High resolution valence-band XPS spectra of the non-conductors quartz and olivine. Physical Review B 72 (2005) 205113-1-201113-13
46. 3 glass using two-dimensional 29Si NMR. Journal of Physical Chemistry 101 (1997) 4004-4008