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0003872521
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Wiely-VCH: Weinheim, Germany
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34547785278
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For analytical data see Supporting Information, the synthesis will be reported in a proceeding full paper
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For analytical data see Supporting Information, the synthesis will be reported in a proceeding full paper.
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17
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34547780241
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hex phase can be supercooled to ca 5°C without crystallization (see Figure S1).
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hex phase can be supercooled to ca 5°C without crystallization (see Figure S1).
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18
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0030164829
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This structure is distinct from all previously reported LC Col hex phases with p6mm symmetry, where columns are embedded in a fluid continuum and also from the hexagonal honeycomb phases reported more recently, see ref 3a-c and the following: Watanabe, J, Sekine, N, Nematsu T, Sone M, Kricheldorf, H. R. Macromolecules 1996, 29, 4816-4818
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hex phases with p6mm symmetry, where columns are embedded in a fluid continuum and also from the hexagonal honeycomb phases reported more recently, see ref 3a-c and the following: Watanabe, J.; Sekine, N.; Nematsu T.; Sone M.; Kricheldorf, H. R. Macromolecules 1996, 29, 4816-4818.
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19
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34547794404
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If the aromatic walls are regarded as net elements connected by nodes formed by the aliphatic tails, this structure corresponds to a 2D tessellation of type (36) where each tile is a triangle and six of them meet at each node. However, if a polygonal shape of the projection of the walls and the nodes is presumed, this structure can be described as a three-color tessellation of the type (4.6.12) composed of rectangular (aromatic, hexagonal (EO, and dodecagonal (aliphatic) tiles see Figure 2c
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6) where each tile is a triangle and six of them meet at each node. However, if a polygonal shape of the projection of the walls and the nodes is presumed, this structure can be described as a three-color tessellation of the type (4.6.12) composed of rectangular (aromatic), hexagonal (EO), and dodecagonal (aliphatic) tiles (see Figure 2c).
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