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Volumn 6, Issue 17, 2000, Pages 3287-3292

Solvent-stabilized alkylrhodium(III) hydride complexes: A special mode of reversible C-H bond elimination involving an agostic intermediate

Author keywords

Agostic interactions; C H activation; Eliminations; Hydrido complexes; Rhodium

Indexed keywords

RHODIUM DERIVATIVE;

EID: 0034282446     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3765(20000901)6:17<3287::AID-CHEM3287>3.0.CO;2-J     Document Type: Article
Times cited : (40)

References (45)
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    • Examples of solvent-stabilized cationic complexes in alkane C-H activation: a) S. S. Stahl, J. A. Labinger, J. E. Bercaw, Angew. Chem. 1998, 110, 2298; Angew. Chem. Int. Ed. 1998, 37, 2180;
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    • Stahl, S.S.1    Labinger, J.A.2    Bercaw, J.E.3
  • 2
    • 0031678723 scopus 로고    scopus 로고
    • Examples of solvent-stabilized cationic complexes in alkane C-H activation: a) S. S. Stahl, J. A. Labinger, J. E. Bercaw, Angew. Chem. 1998, 110, 2298; Angew. Chem. Int. Ed. 1998, 37, 2180;
    • (1998) Angew. Chem. Int. Ed. , vol.37 , pp. 2180
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    • For a review see: G. J. P. Britovsek, V. C. Gibson, D. F. Wass, Angew. Chem. 1999, 111, 448; Angew. Chem. Int. Ed. 1999, 38, 428.
    • (1999) Angew. Chem. Int. Ed. , vol.38 , pp. 428
  • 19
    • 85037487220 scopus 로고    scopus 로고
    • See Experimental Section for the detailed procedure
    • See Experimental Section for the detailed procedure.
  • 20
    • 0000097544 scopus 로고
    • Intramolecular benzylic C-H activation to give alkyl hydride complexes has been reported, for example: a) T. H. Tulip, D. L. Thorn, J. Am. Chem. Soc. 1981, 103, 2448;
    • (1981) J. Am. Chem. Soc. , vol.103 , pp. 2448
    • Tulip, T.H.1    Thorn, D.L.2
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    • 2 were reported: a) S. J. Thompson, P. M. Bailey, C. White, P. M. Maitlis, Angew. Chem. 1976, 88, 506; Angew. Chem. Int. Ed. Engl. 1976, 15, 490;
    • (1976) Angew. Chem. Int. Ed. Engl. , vol.15 , pp. 490
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    • note
    • 1H NMR spectrum of complex 2a in non-deuterated acetone). We believe that preferential crystallization of 2d can be explained by the stabilization and higher rigidity provided by the ketol chelate.
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    • For examples of spin saturation transfer in chemical exchange studies, see: a) M. Portnoy, D. Milstein, Organometallics 1993, 12, 1665;
    • (1993) Organometallics , vol.12 , pp. 1665
    • Portnoy, M.1    Milstein, D.2
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    • b) R. H. Crabtree, Angew. Chem. 1993, 105, 828; Angew. Chem. Int. Ed. Engl. 1993, 32, 789.
    • (1993) Angew. Chem. , vol.105 , pp. 828
    • Crabtree, R.H.1
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    • b) R. H. Crabtree, Angew. Chem. 1993, 105, 828; Angew. Chem. Int. Ed. Engl. 1993, 32, 789.
    • (1993) Angew. Chem. Int. Ed. Engl. , vol.32 , pp. 789


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.