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(a) Kagan, H. B.; Luukas, T. O. Catalytic Asymmetric Sulfide Oxidations. In Transition Metals for Organic Synthesis, 2nd ed.; Beller, M., Bolm, C., Eds.; Wiley-VCH: Weinheim, Germany, 2004; Vol. 2, pp 479-495.
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2 as terminal oxidant, see: (a) Page, P. B.; Heer, J. P.; Bethell, D.; Lund, B. L. Phosphorus, Sulfur Silicon 1999, 153-154, 247-258.
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2O/CHP system: Brunel, J.-M.; Diter, P.; Duetsch, M.; Kagan, H. B. J. Org. Chem. 1995, 60, 8086-8088.
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Recently, we found that oxidation of methyl n-octyl sulfide using Ti(salen) catalyst proceeded with 91% ee: Matsumoto, K.; Saito, B.; Katsuki, T. Chem. Commun. 2007, advance articles.
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(b) Recently, we found that oxidation of methyl n-octyl sulfide using Ti(salen) catalyst proceeded with 91% ee: Matsumoto, K.; Saito, B.; Katsuki, T. Chem. Commun. 2007, advance articles.
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Yamaguchi, T.; Matsumoto, K.; Saito, B.; Katsuki, T. Angew. Chem., Int. Ed. 2007, 46, 4729-4731.
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2 system, see: Sawada, Y.; Matsumoto, K.; Kondo, S.; Watanabe, H.; Ozawa, T.; Suzuki, K.; Saito, B.; Katsuki, T. Angew. Chem., Int. Ed. 2006, 45, 3478-3480.
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2 system, see: Sawada, Y.; Matsumoto, K.; Kondo, S.; Watanabe, H.; Ozawa, T.; Suzuki, K.; Saito, B.; Katsuki, T. Angew. Chem., Int. Ed. 2006, 45, 3478-3480.
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Bolm, C.; Legros, J.; Paih, J. L.; Zani, L. Chem. Rev. 2004, 104, 6217-6254.
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It has been reported that Fe(salen) complexes catalyze oxidation enantioselectively, only when PhIO is used as the oxidant, Bryliakov, K. P, Talsi, E. P. Angew. Chem, Int. Ed. 2004, 43, 5228-5230
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It has been reported that Fe(salen) complexes catalyze oxidation enantioselectively, only when PhIO is used as the oxidant.: Bryliakov, K. P.; Talsi, E. P. Angew. Chem., Int. Ed. 2004, 43, 5228-5230.
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2 was slightly decomposed under the conditions (see Supporting Information).
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2 was slightly decomposed under the conditions (see Supporting Information).
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For recent examples of kinetic resolution of racemic sulfoxide, see: a
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For recent examples of kinetic resolution of racemic sulfoxide, see: (a) Thakur, V. V.; Sudalai, A. Tetrahedron: Asymmetry 2003, 14, 407-410.
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(b) Mohammadpoor-Baltork, I.; Hill, M.; Caggiano, L.; Jackson, R. F. W. Synlett 2006, 3540-3544.
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