Oxidative kinetic resolution of alkyl aryl sulfoxides

Synlett

Volumn , Issue 20, 2006, Pages 3540-3544

  Mohammadpoor Baltork, Iraj ^a   Hill, Mathias ^a   Caggiano, Lorenzo ^a   Jackson, Richard F W ^a  

^a UNIVERSITY OF SHEFFIELD   (United Kingdom)

Author keywords

Asymmetric catalysis; Kinetic resolution; Oxidation; Schiff bases; Sulfoxides

Indexed keywords

CHLOROFORM; SCHIFF BASE; SOLVENT; SULFONE; SULFOXIDE; TOLUENE;

ARTICLE; ASYMMETRIC CATALYSIS; CHEMICAL ANALYSIS; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; CHIRALITY; ENANTIOMER; OXIDATION; RACEMIZATION; SYNTHESIS; TEMPERATURE;

EID: 33846526693     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2006-958409     Document Type: Article

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43. In our experience, use of 23 mL of solvent per mmol of substrate as originally reported results in slow reactions and much poorer yields, a problem that can be overcome by drastically reducing the amount of solvent. Alonso and Nájera have made similar observations when conducting larger-scale reactions: Alonso D. A. and Nájera, C., personal communication from Alonso, D. A., August 2006.