One-pot chemoenzymatic cascade polymerization under kinetic resolution conditions

Macromolecules

Volumn 37, Issue 24, 2004, Pages 8973-8977

  Van As, Bart A C ^c   Thomassen, Paul ^a   Kalra, Bhanu ^b   Gross, Richard A ^b   Meijer, E W ^c   Palmans, Anja R A ^c   Heise, Andreas ^a  

^a DSM RESEARCH   (Netherlands)

^b POLYTECHNIC UNIVERSITY   (United States)

^c EINDHOVEN UNIVERSITY OF TECHNOLOGY   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

ATOM-TRANSFER RADICAL POLYMERIZATION (ATRP); ENANTIOMERS; ENZYMATIC RESOLUTION POLYMERIZATION; GEL PERMEATION CHROMATOGRAPHY (GPC); POLY(CAPROLACTONE);

CATALYSIS; DIFFERENTIAL SCANNING CALORIMETRY; DISTILLATION; ENZYMES; FILTRATION; FREE RADICAL POLYMERIZATION; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; MIXTURES; MOLECULAR SIEVES; MONOMERS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYSTYRENES; PRECIPITATION (CHEMICAL); REACTION KINETICS; RING OPENING POLYMERIZATION; SYNTHESIS (CHEMICAL);

BLOCK COPOLYMERS;

EID: 10044268687     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma048827r     Document Type: Article

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26. Although it is known that nitroxide polymerization is most effective at 120°C, a lower temperature of 95°C was applied here to maintain enzyme activity for possible completion of the eROP. A higher reaction temperature would, however, significantly shorten the reaction time for the nitroxide-mediated polymerization. For reasons of comparability, a reaction temperature of 95°C was also applied in the chemoenzymatic cascade resolution polymerization.