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Volumn 5, Issue 10, 2007, Pages 1595-1600

Entering the leinamycin rearrangement via 2-(trimethylsilyl)ethyl sulfoxides

Author keywords

[No Author keywords available]

Indexed keywords

ALKYLATION; CELL CULTURE; DNA; NEGATIVE IONS; REACTION KINETICS;

EID: 34250704289     PISSN: 14770520     EISSN: None     Source Type: Journal    
DOI: 10.1039/b701179b     Document Type: Article
Times cited : (13)

References (41)
  • 35
    • 23744499223 scopus 로고    scopus 로고
    • For a related example involving intramolecular attack of an α-effect nucleophile, hydroxylamine (RNHOH), on a methyl ester, see:
    • S. Sivaramakrishnan K. Keerthi K. S. Gates J. Am. Chem. Soc. 2005 127 10830 10831
    • (2005) J. Am. Chem. Soc. , vol.127 , pp. 10830-10831
    • Sivaramakrishnan, S.1    Keerthi, K.2    Gates, K.S.3
  • 36
    • 0342982507 scopus 로고
    • Added KF has no effect on either the rates or yields of these reactions, presumably because hydration of the fluoride ion in aqueous solution diminishes the rate of its reaction with the 2-(trimethylsilyl)ethyl group. For example, see:
    • B. G. Cox D. M. A. Grieve A. E. A. Porter J. Chem. Soc., Perkin Trans. 2 1975 1512 1515
    • (1975) J. Chem. Soc., Perkin Trans. 2 , pp. 1512-1515
    • Cox, B.G.1    Grieve, D.M.A.2    Porter, A.E.A.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.