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Volumn 42, Issue 3, 2003, Pages 340-343

Nitrido ruthenium porphyrins: Synthesis, characterization, and amination reactions with hydrocarbon or silyl enol ethers

Author keywords

Amination; N ligands; Porphyrinoids; Ruthenium; Structure elucidation

Indexed keywords

AMINATION; AMINES; COMPOSITION; ETHERS; SYNTHESIS (CHEMICAL);

EID: 0037455261     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200390111     Document Type: Article
Times cited : (75)

References (55)
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    • 2O (see: Z.-Y. Li, C.-M. Che, C.-K. Poon, Wuhan Univ. J Nat. Sci. 1996, 1, 89), the "nitrido" species (which was not structurally characterized) should be reformulated as a hexacoordinate {Ru(NO)} complex, [Ru(4-Cl-tpp)(NO)], according to its UV/Vis spectral data (Soret band: 412 nm, β band: 558 nm).
    • (1996) Wuhan Univ. J. Nat. Sci. , vol.1 , pp. 89
    • Li, Z.-Y.1    Che, C.-M.2    Poon, C.-K.3
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    • 0030772607 scopus 로고    scopus 로고
    • e) J. Du Bois, C. S. Tomooka, J. Hong, E. M. Carreira, M. W. Day, Angew. Chem. 1997, 109, 1722; Angew. Chem. Int. Ed. Engl. 1997, 36, 1645;
    • (1997) Angew. Chem. Int. Ed. Engl. , vol.36 , pp. 1645
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    • f) S. Minakata, T. Ando, M. Nishimura, I. Ryu, M. Komatsu, Angew. Chem. 1998, 110, 3596; Angew. Chem. Int. Ed. 1998, 37, 3392.
    • (1998) Angew. Chem. Int. Ed. , vol.37 , pp. 3392
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    • b) K. Dehnicke, J. Strähle, Angew. Chem. 1992, 104, 978; Angew. Chem. Int. Ed. Engl. 1992, 31, 955.
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  • 43
    • 0348149081 scopus 로고    scopus 로고
    • note
    • 2tpfpp: meso-tetrakis(pentafluorophenyl)porphyrin, NBS: N-bromosuccinimide, Ts = p-toluenesulfonyl.
  • 46
    • 0346258241 scopus 로고    scopus 로고
    • note
    • As tmp is a sterically encumbered porphyrin, whereas 3,4,5- MeO-tpp is basically a sterically unencumbered porphyrin ligand (the latter can not prevent formation of dinuclear μ-oxo ruthenium porphyrins), yet both of them gave nitrido ruthenium porphyrin 1 in similar yields, the steric properties of porphyrin ligands should have a minor effect on the Ru≡N formation from reaction (2).
  • 48
    • 0346258242 scopus 로고    scopus 로고
    • note
    • CCDC-193042 (1b) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: (+44)1223-336-033; or deposit @ccdc.cam.ac.uk).
  • 50
    • 37049141038 scopus 로고
    • 2L = 2,6-bis(2-hydroxy-2,2-diphenylethyl)-pyridine, prepared as described in ref. [15]) with TFAA and the silyl enol ethers shown in Table 1 under the conditions similar to those for 1a/1b but obtained no amination products from the reaction mixtures.
    • (1973) J. Chem. Soc. Dalton Trans. , pp. 1315
    • Griffith, W.P.1    Pawson, D.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.