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2tpfpp: meso-tetrakis(pentafluorophenyl)porphyrin, NBS: N-bromosuccinimide, Ts = p-toluenesulfonyl.
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46
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0346258241
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note
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As tmp is a sterically encumbered porphyrin, whereas 3,4,5- MeO-tpp is basically a sterically unencumbered porphyrin ligand (the latter can not prevent formation of dinuclear μ-oxo ruthenium porphyrins), yet both of them gave nitrido ruthenium porphyrin 1 in similar yields, the steric properties of porphyrin ligands should have a minor effect on the Ru≡N formation from reaction (2).
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47
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CCDC-193042 (1b) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: (+44)1223-336-033; or deposit @ccdc.cam.ac.uk).
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