Stabilization of high-valent terminal-oxo complexes: Interplay of d-orbital occupancy and coordination geometry

Journal of the American Chemical Society

Volumn 118, Issue 2, 1996, Pages 481-482

  Fackler, Nathanael L P ^a   Zhang, Songsheng ^a   O'Halloran, Thomas V ^a,b  

^a NORTHWESTERN UNIVERSITY   (United States)

^b NORTHWESTERN UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0344595256     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja953051i     Document Type: Article

References (29)

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12. 8) value 0.035 (0.036).
13. w) value 0.024 (0.031).
14. -1).
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20. -1.
21. N4 = 16.8°.
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26. 6 as solvent. Benzene backbone H. 6.7 and 8.3 ppm (q); gem diphenyl H, 7.6 and 7.7 ppm (d), 7.0-7.1 ppm (m).
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29. 3P=O/ Ru.