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34249861703
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For examples where protected 1-deoxynojirimycin derivatives have been useful, see:
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For a recent review on synthesis of iminosugars containing six-membered rings, see:. Afarinkia K., and Bahar A. Tetrahedron: Asymmetry 16 (2005) 1239-1287
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35
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34249845746
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note
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The yield of the azide via the cyclic sulfite reported was the best achieved. However, in the hands of other co-workers lower yields were obtained (∼60%, two steps).
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-
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36
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34249859589
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note
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For the deprotection on a 10 g scale, the use of Dowex-50-X8 was found to be more efficient than Dowex-50-X4.
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37
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34249849531
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For previous syntheses of 1-deoxynojirimycin from l-sorbose, see:
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The conversion of an N-Boc group in presence of TBDMSOTf to a silyl carbamate has been reported.
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