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Unless stated otherwise, throughout the present study the working CO pressure will be expressed in bar above atmospheric pressure
-
Unless stated otherwise, throughout the present study the working CO pressure will be expressed in bar above atmospheric pressure.
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47
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The stirring speed was set to 1100 rpm for all of the kinetic measurements. A cross-shaped magnetic stirrer was used throughout the present study. For the effect of stirring speed on asymmetric hydrogenations see: Sun, Y.; Landau, R. N.; Wang, J.; LeBlond, C.; Blackmond, D. G. J. Am. Chem. Soc. 1996, 118, 1348-1353.
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The stirring speed was set to 1100 rpm for all of the kinetic measurements. A cross-shaped magnetic stirrer was used throughout the present study. For the effect of stirring speed on asymmetric hydrogenations see: Sun, Y.; Landau, R. N.; Wang, J.; LeBlond, C.; Blackmond, D. G. J. Am. Chem. Soc. 1996, 118, 1348-1353.
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33947116189
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8 samples are far more sensitive to moisture and oxygen than the corresponding commercial hexanes-stabilized samples.
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8 samples are far more sensitive to moisture and oxygen than the corresponding commercial hexanes-stabilized samples.
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50
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33947149967
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The rate was obtained from fitting concentration-time data to an exponential curve and differentiating this function to obtain rate-time data
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The rate was obtained from fitting concentration-time data to an exponential curve and differentiating this function to obtain rate-time data.
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Under the present reaction conditions, the dicobalt octacarbonyl complex was never observed by in situ FT-IR as an intermediate in the catalytic PKR
-
Under the present reaction conditions, the dicobalt octacarbonyl complex was never observed by in situ FT-IR as an intermediate in the catalytic PKR.
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Endo coordination of NBD is energetically disfavored by approximately 4.0 kcal/mol, as determined by DFT (B3LYP/LACVP) calculations.
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Endo coordination of NBD is energetically disfavored by approximately 4.0 kcal/mol, as determined by DFT (B3LYP/LACVP) calculations.
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A low overpressure of CO was selected to mimic reactions at atmospheric pressure balloon pressure
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A low overpressure of CO was selected to mimic reactions at atmospheric pressure (balloon pressure).
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