Rh(I)-catalyzed Pauson-Khand reaction and cycloisomerization of allenynes: Selective preparation of monocyclic, bicyclo[m.3.0], and bicyclo[5.2.0] ring systems

Journal of Organic Chemistry

Volumn 70, Issue 18, 2005, Pages 7159-7171

  Mukai, Chisato ^a   Inagaki, Fuyuhiko ^a   Yoshida, Tatsunori ^a   Yoshitani, Katsuya ^a   Hara, Yasuyuki ^a   Kitagaki, Shinji ^a  

^a KANAZAWA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL REACTIONS; DERIVATIVES; ISOMERIZATION; NITROGEN; ORGANIC COMPOUNDS; RHODIUM;

4-PHENYLSULFONYLNONA-2,3-DIEN-8-YNES; ALLENYNES; CYCLOHEPTENE DERIVATIVES; RH(I)-CATALYZED PAUSON-KHAND REACTIONS;

CATALYSIS;

4 PHENYLSULFONYLNONA 2,3 DIEN 8 YNE; ALKADIENE; ALLENE DERIVATIVE; AZABICYCLO[5.3.0]DECADIENONE; BICYCLO COMPOUND; BICYCLO[5.2.0]NONENE; CYCLOHEPTENE; CYCLOHEXENE DERIVATIVE; OXABICYCLO[5.3.0]DECADIENONE; RHODIUM; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CYCLIZATION; ISOMERIZATION; MOLECULAR MODEL; PAUSON KHAND REACTION; RING CLOSING METATHESIS; SYNTHESIS;

EID: 24144488325     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo050770z     Document Type: Article

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64. 1H NMR.
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66. Compounds 36 were prepared by the standard procedure described in this paper; see the Supporting Information.
67. Compounds 12d,e were exposed to xylene refluxing conditions leading to an intractable mixture.
68. b bond could not be detected.