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Volumn 127, Issue 40, 2005, Pages 13776-13777

Photochemical generation of a highly reactive iron-oxo intermediate. A true iron(v)-oxo species?

Author keywords

[No Author keywords available]

Indexed keywords

ACETONITRILE; CORROLE DERIVATIVE; CYCLOHEXENE DERIVATIVE; HYDROCHLORIC ACID; IRON; IRON COMPLEX; LIGAND; PORPHYRIN DERIVATIVE; RADICAL; SILVER CHLORATE; SILVER DERIVATIVE; SILVER NITRATE; UNCLASSIFIED DRUG;

EID: 26444486355     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0542439     Document Type: Article
Times cited : (95)

References (29)
  • 4
    • 0001405437 scopus 로고
    • Wilkinson, G., Stone, F. G. A., Abel, E. W., Hegedus, L. S., Eds.; Pergamon: New York
    • Jacobsen, E. N. In Comprehensive Organometallic Chemistry II; Wilkinson, G., Stone, F. G. A., Abel, E. W., Hegedus, L. S., Eds.; Pergamon: New York, 1995; Vol. 12, pp 1097-1135.
    • (1995) Comprehensive Organometallic Chemistry II , vol.12 , pp. 1097-1135
    • Jacobsen, E.N.1
  • 11
  • 19
    • 0033531758 scopus 로고    scopus 로고
    • Corrole-iron complexes are known to be oxidation catalysts with sacrificial oxidants, but no iron-oxo transients have been detected in such studies; see: Gross, Z.; Simkhovich, L.; Galili, N. Chem. Commun. 1999, 599.
    • (1999) Chem. Commun. , pp. 599
    • Gross, Z.1    Simkhovich, L.2    Galili, N.3
  • 21
    • 0035793809 scopus 로고    scopus 로고
    • max = 650 nm) consistent with a ligand radical cation. Compounds 2 were ESR silent, as expected for Fe(IV) species with broad absorbances, and the ESR spectrum of 3a had a signal at g = 4.5. The spectra allow us to rule out iron(IV) corrole radical cations and the known neutral iron(III) species as structures of 2 and 3, respectively. Spectra are shown in the Supporting Information. For an example of a metal corrole radical cation complex, see: Simkhovich, L.; Mahammed, A.; Goldberg, I.; Gross, Z. Chem.-Eur. J. 2001, 7, 1041.
    • (2001) Chem.-Eur. J. , vol.7 , pp. 1041
    • Simkhovich, L.1    Mahammed, A.2    Goldberg, I.3    Gross, Z.4
  • 22
    • 1942439087 scopus 로고    scopus 로고
    • For discussions of reactivities of corrole- and related corrolazine-manganese(V)-oxo species, see: (a) Gross, Z.; Gray, H. B. Adv. Synth. Catal. 2004, 346, 165.
    • (2004) Adv. Synth. Catal. , vol.346 , pp. 165
    • Gross, Z.1    Gray, H.B.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.