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Volumn , Issue 7, 2007, Pages 713-715

From inconsistent results to high speed hydrosilylation

Author keywords

[No Author keywords available]

Indexed keywords

ACETOPHENONE; HYDROGEN; RHODIUM; WATER;

EID: 33846912963     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b617413b     Document Type: Article
Times cited : (13)

References (31)
  • 3
    • 0003400107 scopus 로고
    • Wiley, New York, For the highly enantioselective rhodium-catalysed hydrosilylation of ketones using diphosphine ligands, see:
    • R. Noyori, Asymmetric Catalysis in Organic Synthesis, Wiley, New York, 1994
    • (1994) Asymmetric Catalysis in Organic Synthesis
    • Noyori, R.1
  • 14
    • 0000011537 scopus 로고
    • Lowering the temperature generally results in higher enantioselectivity (see ref. 2 and ref. 3). Nevertheless, some exceptions have been reported:
    • H. Nishiyama M. Kondo T. Nakamura K. Ito Organometallics 1991 10 500
    • (1991) Organometallics , vol.10 , pp. 500
    • Nishiyama, H.1    Kondo, M.2    Nakamura, T.3    Ito, K.4
  • 18
    • 33846896488 scopus 로고    scopus 로고
    • o-dppbe = ortho-Bis(diphenylphosphino)benzene
    • o-dppbe = ortho-Bis(diphenylphosphino)benzene
  • 19
    • 33846897269 scopus 로고    scopus 로고
    • Deguphos = 3,4-Bis(diphenylphosphino)-1-benzylpyrrolidine
    • Deguphos = 3,4-Bis(diphenylphosphino)-1-benzylpyrrolidine
  • 20
    • 0001453617 scopus 로고
    • Highly active mono(phosphine)rhodium catalysts for the hydrosilylation of ketones have been recently described:
    • T. C. Bedard J. Y. Corey J. Organomet. Chem. 1992 428 315
    • (1992) J. Organomet. Chem. , vol.428 , pp. 315
    • Bedard, T.C.1    Corey, J.Y.2
  • 25
  • 26
    • 2542473311 scopus 로고    scopus 로고
    • A mechanism analogous to the one described by Fryzuk, involving the formation of dinuclear rhodium complexes, cannot be completely ruled out. However, the low concentration of the rhodium complex in the reaction mixture strongly supports a mechanism occurring at a rhodium centre:
    • L. Turculet J. D. Feldman T. D. Tilley Organometallics 2004 23 2488
    • (2004) Organometallics , vol.23 , pp. 2488
    • Turculet, L.1    Feldman, J.D.2    Tilley, T.D.3
  • 31
    • 33846934794 scopus 로고    scopus 로고
    • dppe = Bis(diphenylphosphino)ethane
    • dppe = Bis(diphenylphosphino)ethane


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.