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Volumn 15, Issue 13, 1996, Pages 2871-2880

Reactions of secondary silanes with [{Pr2iPCH2CH2PPr2 i}Rh]2(μ-H)2. A series of dinuclear silyl-hydride complexes and their possible involvement in the catalytic hydrosilylation of olefins

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EID: 0001005404     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om950450d     Document Type: Article
Times cited : (50)

References (45)
  • 26
    • 85088543181 scopus 로고    scopus 로고
    • note
    • 29Si NMR spectra for 2a and 2b show signals that are too broad and poorly resolved to give any information on the connectivity at silicon in these complexes, even at low temperature (for 2a). This is probably due to the extensive coupling of silicon to other spins, combined with the fluxionality of the complexes.
  • 40
    • 5344258490 scopus 로고    scopus 로고
    • note
    • It should be noted that while this result appears to indicate that no fragmentation is occurring, a similar result would be obtained if only one of the two complexes underwent fragmentation. In the absence of kinetic data it is impossible to prove the participation of a dinuclear species in the catalytic cycle.
  • 45
    • 0003174819 scopus 로고
    • Kynoch Press: Birmingham, U.K. (present distributor Kluwer Academic Publishers: Boston, MA)
    • International Tables for X-Ray Crystallography; Kynoch Press: Birmingham, U.K. (present distributor Kluwer Academic Publishers: Boston, MA), 1974; Vol. IV, pp 99-102, 149.
    • (1974) International Tables for X-Ray Crystallography , vol.4 , pp. 99-102


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.