Analysis of the enantioselectivities and initial rates of the hydrosilylation of acetophenone catalyzed by [Rh(cod)Cl]2/(chiral diphosphine). The quantitative analysis of ligand effects

Journal of Organometallic Chemistry

Volumn 671, Issue 1-2, 2003, Pages 13-26

  Reyes, Clementina ^a   Prock, Alfred ^a   Giering, Warren P ^a  

^a BOSTON UNIVERSITY   (United States)

Author keywords

Asymmetric catalysis; Hydrosilylation; Ketone; Kinetics; Ligand effects; Quantitative analysis of ligand effects

Indexed keywords

BENZENE; BENZENE REFINING; CATALYSIS; ENANTIOSELECTIVITY; ENZYME KINETICS; HYDROSILYLATION; KETONES; LIGANDS; RHODIUM; SILANES;

ACETOPHENONES; ASYMMETRIC CATALYSIS; CATALYTIC SYSTEM; DIPHOSPHINES; INITIAL RATE; ISOQUINOLINES; LIGAND EFFECT; STERIC EFFECT;

CHELATION;

ACETOPHENONE DERIVATIVE; BENZENE DERIVATIVE; BUTANE; KETONE DERIVATIVE; LIGAND; PHOSPHINE DERIVATIVE; QUINOLONE DERIVATIVE; RUTHENIUM DERIVATIVE; SILANE;

ARTICLE; CATALYSIS; CHEMICAL ANALYSIS; CHEMICAL REACTION; CHIRALITY; CONTROLLED STUDY; ELECTROCHEMISTRY; ENANTIOSELECTIVITY; HYDROSILYLATION; QUANTITATIVE ANALYSIS; SILYLATION;

GADUS MORHUA;

EID: 0037387881     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(02)02221-0     Document Type: Article

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