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Although we have not formally excluded the possibility of a mechanism involving Zr-O bond cleavage, this is very unlikely under these conditions
-
Although we have not formally excluded the possibility of a mechanism involving Zr-O bond cleavage, this is very unlikely under these conditions.
-
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54
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33846378332
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Line shape analysis was carried out using WIN-DYNA 32, version 1.01, release 981101, Bruker Analytik GmbH, 1994-1998
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Line shape analysis was carried out using WIN-DYNA 32, version 1.01, release 981101, Bruker Analytik GmbH, 1994-1998.
-
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58
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The standard errors involved in the Eyring plot were calculated using Origin 7.0. The error involved in the single equation is based upon an error in T of ±1 K and an error in k of ±40%. This error value for k comes from the largest deviation from the linear fit in the Eyring plot.
-
The standard errors involved in the Eyring plot were calculated using Origin 7.0. The error involved in the single equation is based upon an error in T of ±1 K and an error in k of ±40%. This error value for k comes from the largest deviation from the linear fit in the Eyring plot.
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2] would be instructive, but unfortunately we have thus far been unable to synthesise these compounds (vide supra).
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2] would be instructive, but unfortunately we have thus far been unable to synthesise these compounds (vide supra).
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In the case of 2 the reaction took place overnight, although the product alkyl cation was remarkably stable, existing at ambient temperatures for several days in solution before noticeable decomposition
-
In the case of 2 the reaction took place overnight, although the product alkyl cation was remarkably stable, existing at ambient temperatures for several days in solution before noticeable decomposition.
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66
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These studies were carried out without consideration of counteranion and solvent effects
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