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Crystal data for CUK-1: C14H26Co3N 2O19, Mr, 685.01 g mol-1, monoclinic, C2/c, a, 17.0783(5, b, 14.3338(4, c, 10.7738(4) Å, β, 106.3970(11)°, V, 2530.13(14) Å, 2θmax, 27.48°, λ, 0.71073, T, 180(2) K. 8890 reflections were collected, of which 2889 were unique (Rint, 0.0424, The structure was solved by direct methods and refined by full-matrix least squares on F2. R1, 0.0495 (I > 2σ(I, wR2, 0.0877 (all data, max/min residual electron density, 0.735/-0.502 e Å-3. Crystal data for CUK-2: C12H12Co2N2O 7S2, Mr, 472.17 g mol-1, orthorhombic, C2221, a, 11.0477(3, b, 13.59184, c
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Crystal data for dehydrated CUK-1: C14H8Co 3N3O10, Mr, 541.01 g mol-1, monoclinic, C2/c, a, 18.1020(7, b, 12.7694(5, c, 10.9701(5) Å, β, 103.4004(16)°, V, 2466.72(18) Å3, 2θmax, 27.54°, λ, 0.71073 Å, T, 375(2) K. 7431 reflections were collected, of which 2818 were unique (Rint, 0.0357, The structure was solved by direct methods and refined by full-matrix least squares on F2. R1=0.0471 (I>.2σ(I, wR2, 0.0695 all data, max/min residual electron density, 0.402/-0.335 e Å-3. Crystal data for dehydrated CUK-2: C12H 6Co2N2O4S2, M r, 424.17 g mol-1,orthorhombic, C2221, a, 11.122
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