Hydrogen storage in the dehydrated prussian blue analogues M 3[Co(CN)6]2 (M = Mn, Fe, Co, Ni, Cu, Zn)

Journal of the American Chemical Society

Volumn 127, Issue 18, 2005, Pages 6506-6507

  Kaye, Steven S ^a   Long, Jeffrey R ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COBALT COMPLEX; COPPER COMPLEX; FERRIC FERROCYANIDE; HYDROGEN; IRON COMPLEX; MANGANESE; NICKEL COMPLEX; ZINC COMPLEX;

ADSORPTION; ARTICLE; CHEMICAL INTERACTION; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; ISOTHERM; POROSITY; X RAY POWDER DIFFRACTION;

EID: 18644366670     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja051168t     Document Type: Article

References (24)

1. Schlapbach, L.; Züttel, A. Nature 2001, 414, 353 and references therein.
2. Hirscher, M.; Becher, M.; Haluska, M.; von Zeppelin, F.; Chen, X.; Dettlaff-Weglikowska, U.; Roth, S. J. Alloys Compd. 2003, 356-357, 433.
3. (a) Sandrock, G.; Gross, K.; Thomas, G.; Jensen, C.; Meeker, D.; Takara, S. J. Alloys Compd. 2002, 330, 696.
4. (b) Bogdanovic, B.; Felderhoff, M.; Kaskel, S.; Pommerin, A.; Schlichte, K.; Schüth, F. Adv. Mater. 2003, 15, 1012.
5. Sandrock, G.; Thomas, G. Appl. Phys. 2001, 72, 153.
6. (a) Rosi, N. L.; Eckert, J.; Eddaoudi, M.; Vodak, D. T.; Kim, J.; O'Keeffe, M.; Yaghi, O. M. Science 2003, 300, 1127.
7. (b) Rowsell, J. L.; Millward, A. R.; Park, K. S.; Yaghi, O. M. J. Am. Chem. Soc. 2004, 126, 5666.
8. (a) Ferey, G.; Latroche, M.; Serre, C.; Millange, F.; Loiseau, T.; Percheron-Guegan, A. Chem. Commun. 2003, 2976.
9. (b) Dybtsev, D. N.; Chun, H.; Yoon, S. H.; Kim, D.; Kim, K. J. Am. Chem. Soc. 2004, 126, 32.
10. (c) Dybtsev, D. N.; Chun, H.; Kim, K. Angew. Chem., Int. Ed. 2004, 43, 5033.
11. (d) Pan, L.; Sander, M. B.; Huang, X.; Li, J.; Smith, M.; Bittner, E.; Bockrath, B.; Johnson, J. K. J. Am. Chem. Soc. 2004, 126, 1308.
12. (e) Zhao, X.; Xiao, B.; Fletcher, A. J.; Thomas, K. M.; Bradshaw, D.; Rosseinsky, M. J. Science 2004, 306, 1012.
13. (f) Kesanli, B.; Cui, Y.; Smith, M. R.; Bittner, E. W.; Bockrath, B. C.; Lin, W. Angew. Chem., Int. Ed. 2005, 44, 72.
14. (g) Kubota, Y.; Takata, M.; Matsuda, R.; Kitaura, R.; Kitagawa, S.; Kato, K.; Sakata, M.; Kobayashi, T. C. Angew. Chem., Int. Ed. 2005, 44, 920.
15. Buser, H. J.; Schwarzenbach, D.; Petter, W.; Ludi, A. Inorg. Chem. 1977, 16, 2704.
16. Herren, F.; Fischer, P.; Ludi, A.; Haelg, W. Inorg. Chem. 1980, 19, 956.
17. Shriver, D. F.; Brown, D. B. Inorg. Chem. 1969, 8, 42.
18. Bennett, M. V.; Beauvais, L. G.; Shores, M. P.; Long, J. R. J. Am. Chem. Soc. 2001, 123, 8022.
19. Chester, A. W.; Clement, P.; Han, S. U.S. Patent 2000/6, 136, 291A.
20. Roquerol, F.; Rouquerol J.; Sing, K. Adsorption by Powders and Solids: Principles, Methodology, and Applications: Academic Press: London, 1999.
21. Yang, R. T. Gas Separation by Adsorption Processes; Butterworth: Boston, 1997.
22. 2 storage capacity of 4.8 wt %; however, this value is not very reliable since only a small fraction of the sorption isotherm is available for fitting.
23. Irving, H.; Williams, R. J. Nature 1948, 162, 146.
24. Note that the enthalpies of adsorption for most of the Prussian blue analogues are also higher than the 5.0-6.4 kJ/mol measured for the activated carbon AX-21: Benard, P.; Chahine, R. Langmuir 2001, 17, 1950.