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For synthesis of similar compounds, see
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For synthesis of similar compounds, see: Srinivasan, V.; Jebaratnam, D. J.; Budil, D. E. J. Org. Chem. 1999, 64, 5644.
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33845931588
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4 and (R)-BINAP gave the corresponding adduct with >99% ee. The origin of this result is being investigated in our laboratory.
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4 and (R)-BINAP gave the corresponding adduct with >99% ee. The origin of this result is being investigated in our laboratory.
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40
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33845915996
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Reactions using the following metal catalysts were checked on TLC: A1, B, Mg, Zn, Ti, Sc, Hf, Yb, Zr, In, La. None of them accelerated the reaction.
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Reactions using the following metal catalysts were checked on TLC: A1, B, Mg, Zn, Ti, Sc, Hf, Yb, Zr, In, La. None of them accelerated the reaction.
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For synthesis of silyloxydienes, see: a
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For synthesis of silyloxydienes, see: (a) Nakashima, D.; Yamamoto, H. J. Am. Chem. Soc. 2006, 128, 9626.
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44
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33845928214
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Excess amount of AcOH was necessary to avoid epimerization of the methyl group via retro-Michael reaction
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Excess amount of AcOH was necessary to avoid epimerization of the methyl group via retro-Michael reaction.
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45
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2-mediated cleavage of the N-N bond with trifluoroacetyl group, see: (a) Chowdari, N. S.; Barbas, C. F., III. Org. Lett. 2005, 7, 867.
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2-mediated cleavage of the N-N bond with trifluoroacetyl group, see: (a) Chowdari, N. S.; Barbas, C. F., III. Org. Lett. 2005, 7, 867.
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